An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Three atoms of oxygen are condensed into the space of two atoms
of ozone, or three molecules of O are condensed into two
molecules of ozone, or three liters of O are condensed into two
liters of ozone. Ozone is thus formed by oxidizing ordinary
oxygen. 02 + O = 03. This takes place during thunder storms and
in artificial electrical discharges. The quantity of ozone
produced is small, five per cent being the maximum, and the usual
quantity is far less than that.
Ozone is a powerful oxidizing agent, and will change S, P, and As
into their ic acids. Cotton cloth was formerly bleached, and
linen is now bleached, by spreading it on the grass and leaving
it for weeks to be acted on by ozone, which is usually present in
the air in small quantities, especially in the country. Ozone is
a disinfectant, like other bleaching agents, and serves to clear
the air of noxious gases and germs of infectious diseases. So
much ozone is reduced in this way that the air of cities contains
less of it than country air. A third is consumed in uniting with
the substance which it oxidizes, while two-thirds are changed
into oxygen, as in Experiment 79.
It is unhealthful to breathe much ozone, but a little in the air
is desirable for disinfection.
Ozone will cause the inert N of the air to unite with H, to form
ammonia. No other agent capable of doing this is known, so that
all the NH3 in the air, in fact all ammonium compounds taken up
by plants from soils and fertilizers, may have been made
originally through the agency of ozone. At a low temperature
ozone has been liquefied. It is then distinctly blue.
Electrolysis of water is the best mode of preparing this
substance in quantity. When prepared from P it is mixed with
P2O3.
Chapter XXVII.
CHEMISTRY OF THE ATMOSPHERE.
130. Constituents.--The four chief constituents of the atmosphere
are N, O, H2O, CO2, in the order of their abundance. What
experiments show the presence of N, O, and CO2 in the air? Set a
pitcher of ice water in a warm room, and the moisture that
collects on the outside is deposited from the air. This shows the
presence of H2O. Rain, clouds, fog, and dew prove the same. H2SO4
and CaCl2, on exposure to air, take up water. Experiment 18 shows
that there is not far from four times as much N as O by volume in
air. Hence if the atmosphere were a compound of N and O, and the
proportion of four to one were exact, its symbol would be N4O.
131. Air not a Compound.--The following facts show that air is
not a compound, but rather a mixture of these gases.
1. The proportion of N and O in the air, though it does not vary
much, is not always exactly the same. This could not be true if
it were a compound. Why?
2. If N4O were dissolved in water, the N would be four times the
O in volume; but when air is dissolved, less than twice as much N
as O is taken up.
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