An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Experiment 82.--Examine a candle flame, holding a dark object
behind it. Note three distinct portions: (1) a colorless interior
about the wick, (2) a yellow light-giving portion beyond that,
(3) a thin blue envelope outside of all, and scarcely
discernible. Hold a small stick across the flame so that it may
lie in all three parts, and observe that no combustion takes
place in the inner portion.
142. Explanation.--A candle of paraffine, or tallow, is chiefly
composed of compounds of C and H, in the solid state. The burning
wick melts the solid; the liquid is then drawn up by the wick
till the heat vaporizes and decomposes it, and O of the air comes
in contact with the outer heated portion of gas, and burns it
completely. Air tends to penetrate the whole body of the flame,
but only N can pass through uncombined, for the O that is left
after combustion in the outer portion seizes upon the compounds
of C and H in the next, or yellow, part. There is not enough O
here for complete combustion; at this temperature H burns before
C, and the latter is set free. In that state it is of course a
solid. Now an incandescent solid, or one glowing with heat, gives
light, while the combustion of a gas gives scarcely any light,
though it may produce great heat. While C in the middle flame is
glowing, during the moment of its dissociation from H, it gives
light. In the outer flame the temperature is high enough to burn
entirely the gaseous compounds of C and H together, so that no
solid C is set free, and hence no light is given except the faint
blue. No combustion takes place in the inner blue cone, because
no O reaches there.
By packing a wick into a cylindrical tin cup 5 or 10 cm high and
4 cm in diameter, containing alcohol, and lighting it, gunpowder
can be held in the middle of the flame in a def. spoon, without
burning. This shows the low temperature of that portion. Burning
P will also be extinguished, thus showing the exclusion of O.
143. Bunsen Flame.
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