An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Gas and O are both present. Evidently, then, the only condition
wanting for combustion is a sufficiently high temperature. The
gauze cools the gas below its kindling- point.
This principle is made use of in the miner's lamp of Davy (Fig.
34). In coal mines a very inflammable gas, CH4, called fire-damp,
issues from the coal. If this collects in large quantities and
mixes with O of the air, a kindling-point is all that is needed
to make a violent explosion. An ordinary lamp would produce this,
but the gauze lamp prevents it; for, though the inside may be
filled with burning gas, CH4, the flame cannot communicate with
the outside.
(Fig 35.) (Fig 36.)
a, reducing flame b, oxidizing flame
146. Oxidizing and Reducing Flames.--The hottest part of a Bunsen
flame is just above the inner blue cone (b, Fig. 36). Evidently
there is more O at that point. If a reducing agent, i.e. a
substance which takes up O, be put into this part of the flame,
the latter will remove the O and appropriate it, forming an
oxide. Cu heated there would become copper oxide. This part is
called the oxidizing flame. The inner blue part of the Bunsen
flame is devoid of O. It ought to remove O from an oxidizing
agent, i.e. a substance which supplies O. If copper oxide be
heated there (a, Fig. 36) by means of a mouth blow-pipe (Fig.
35), the flame will appropriate the O and leave the copper. This
is called the reducing flame. Only the upper part of this blue
central cone has heat enough to act in this way. By using a
prepared piece of metal, to make the flame thin and to shut off
the air, and then blowing the flame with a blow-pipe, greater
strength can be obtained in both oxidizing and reducing flames
(Fig. 36).
147. Combustible and Supporter Interchangeable.-- H was found to
burn in O. H was the combustible, O the supporter. Would O itself
burn in H?--i.e. would the combustible become the supporter, and
the supporter the combustible? As illuminating gas consists
largely of H, and as air is part O, we may try the experiment
with gas and air. Gas will burn in air. Will air burn in gas?
Experiment 85.--Fit a cork with two holes in it to the large end
of a lamp chimney. Through each hole pass a short piece of
tubing, and connect one of these with a rubber tube leading to a
gas-jet. Pass a metallic tube, long enough to reach the top of
the chimney, through the other, so that it will move easily up
and down. Turn on the gas, and light it at the top of the
chimney. Hold the end of the tube passing through the cork in the
flame for a minute, then draw it down to the middle of the
chimney (Fig. 37, a) and finally slowly remove it (b). Note that
O from the air is burning in the gas. Which is the supporter, and
which the combustible in this case? O will burn equally well in
an atmosphere of H, as can be shown by experiment.
148. Explosive Mixture of Gases.
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