An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
If preferred, a flask may be used for a generator instead of a
t.t. Cl can be obtained directly from NaCl by adding H2SO4 (which
produces HCl) and MnO2. 2 NaCl + 2 H2SO4 + MnO2 = MnSO4 + Na2SO4
+ 2 H2O + 2 Cl. Try the experiment, using a t.t. and adding
water.
151. Cl from Bleaching-Powder.
Experiment 88.--Put a few grams of bleaching- powder into a small
beaker, and set this into a larger one. Cover the latter with
pasteboard or paper, through which passes a thistle-tube reaching
into the small beaker (Fig. 40). Pour through the tube a little
H2SO4 dilated with its volume of H2O.
152. Chlorine Water.--A solution of Cl in water is often useful,
and may be made as follows:-- Experiment 89.--To 3 or 4 crystals
of KClO3 add a few drops of HCl. Heat a minute, and when the gas
begins to disengage, pour in 10 cc. H2O, which dissolves the gas.
2 KClO3 + 4 HCl = 2 KCl + Cl2O4 + 2 H2O + 2 Cl.
153. Bleaching Properties.
Experiment 90.--Put into a receiver of Cl, preferably before
generating it, two pieces of Turkey red cloth, one wet, the other
dry; a small piece of printed paper and a written one; also a red
rose or a green leaf, each wet. Note from which the color is
discharged. If it is not discharged from all, put a little H2O
into the receiver, shake it well, and state what ones are
bleached.
Experiment 91.--(1) Add 5 cc. of Cl water to 5 cc. of indigo
solution. (2) Treat in the same way 5 cc. K2Cr2O7 (potassium
dichromate) solution, and record the results.
Indigo, writing-ink, and Turkey red or madder, are vegetable
pigments; printer's ink contains C, and K2Cr2O7 is a mineral
pigment. State what coloring matters Cl will bleach.
154. Disinfecting Power.
Experiment 92.--Pass a little H2S gas from a generator into a
t.t. containing Cl water. Look for a deposit of S. Notice that
the odor of H2S disappears. H2S + 2 Cl = 2 HCl + S.
155. A Supporter of Combustion.
Experiment 93.--Sprinkle into a receiver of Cl a very little fine
powder or filings of Cu, As, or Sb, and notice the combustion.
Observe that here is a case of combustion in which O does not
take part. Chlorides of the metals are of course formed. Write
the reactions. See whether Cl will support the combustion of
paper or of a stick of wood.
Experiment 94.--Warm 2 or 3 cc. of oil of turpentine (C1OH16) in
an evaporating-dish; dip a piece of tissue paper into it, and
very quickly thrust this into a receiver of Cl. It should take
fire and deposit carbon. C1OH16 + 16 Cl = ? Test the moisture on
the sides of the receiver with litmus. Clean the receiver with a
little petroleum.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account