An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
(7) A compound of N and H gas weighs 0.765 g. to the liter. The N
is 14/17 of the whole, the H 3/17. What gas is it? CHAPTER XXXV.
ATOMIC WEIGHT.
174. Definition.--We have seen that the molecular weight of a
compound, as well as of most elements, is obtained from the vapor
density by doubling the latter. It remains to explain how atomic
weights are obtained. The term is rather misleading. The atomic
weight of an element is its least combining weight, the smallest
portion that enters into chemical union, which is, of course, the
weight of an atom.
175. Atomic Weight of Oxygen.--Suppose we wish to find the atomic
weight of oxygen. We must find the smallest proportion by weight
in which it occurs in any compound. This can only be done by
analyzing all the compounds of O that can be vaporized. As
illustrative of these compounds take the six following:--
Wt. of other
Names. V. d. Mol. Wt. Wt. of O. Elem. Symbol.
Carbon monoxide... 14 28 16 12 ?
Carbon dioxide.... 22 44 32 12 ?
Hydrogen monoxide... 9 18 16 2 ?
Nitrogen monoxide... 22 44 16 28 ?
Nitrogen trioxide... 38 76 48 28 ?
Nitrogen pentoxide... 54 108 80 28 ?
176. Molecular Symbols.--From the vapor density of the gases--
column 2--we obtain their molecular weight-- column 3. To find
the proportion of O, it must be separated by chemical means from
its compounds and separately weighed. These relative weights are
given in column 4. Now the smallest weight of O which unites in
any case is its atomic weight. If any compound of O should in
future be found in which its combining weight is 8 or 4, that
would be called its atomic weight. By dividing the numbers in
column 4, wt. of O, by 16, the atomic weight of O, we obtain the
number of O atoms in the molecule. Subtracting the weights of O
from the molecular weights, we have the parts of the other
elements, column 5, and dividing these by the atomic weight of
the respective elements, we have the number of atoms of those
elements, these last, combined with the number of O atoms, give
the symbol. In this way complete the last column.
Show how to get the atomic weight of Cl from these compounds,
arranging them in tabular form, and completing as above: HCl,
KCl, NaCl, ZnCl2, MgCl2; the atomic weight of N in these: N2O,
NO, NH3.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account