An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Few photographers now make their own plates, these being prepared
at large manufactories. The glass is there covered on one side
with a white emulsion of gelatine and AgBr, making what are
called gelatine-bromide plates. This is done in a room dimly
lighted with ruby light. The plates are dried, packed in sealed
boxes, and thus sent to photographers. The artist opens them in
his dark room, similarly lighted, inserts the plates in holders,
film side out, covers with a slide, adjusts to the camera,
previously focused, and makes the exposure to light. The time of
exposure varies with the kind of plate, the lens, and the light,
from several seconds, minutes, or hours, to 1/250 part of a
second in some instantaneous work. In the dark room the plates
are removed and can be at once developed, or kept for any time
away from the light. No change appears in the plate until
development, though the light has done its work.
To develop the plate, it is put into a solution of pyrogallic
acid, the developer, and carbonate of sodium, the motive power in
the process. Other developers are often used. The chemical action
here is somewhat obscure, but those parts of the plates which
were affected by the light are made visible, a part of the AgzBr
being reduced to Ag by the affinity which sodium pyrogallate has
for Br. Ag2Br = 2 Ag + Br. Br is dissolved and Ag is deposited.
When the rather indistinct image begins to fade out, the plate is
dipped for a minute into a solution of alum to harden the
gelatine and prevent it from peeling off (frilling). It is
finally soaked in a solution of sodium thiosulphate (hyposulphite
or hypo), Na2S208. This removes the AgBr that the light has
failed to reduce. The processis called fixing, as the plate may
thereafter be exposed to the light with impunity. It must be left
in this bath till all the white part, best seen on the back of
the plate, disappears. 2AgBr + 3Na2S2O3 = Ag2Na4(S2O3) + 2 NaBr.
Both products are dissolved. It is then thoroughly washed. Any
dark objects become light in the negative, and vice versa. Why?
For the positive, the best linen paper is covered on one side
with albumen, soaked in NaCl solution, dried, and the same side
laid on a solution of AgNO3. What reaction takes place? What is
deposited on the paper, and what is dissolved? This sensitized
paper, when dry, is placed over a negative, film to film, and
exposed in a printing frame to direct sunlight till much darker
than desired in the finished picture. What is dark in the
negative will be light in the positive. Why? The reducing action
of sunlight is similar to that in the negative. Explain it.
Public-domain text, read in full here on John Shaqi.
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