An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
After printing, the picture is toned and fixed. Toning consists
in giving it a rich color by replacing part of the Ag2Cl with
gold from a neutral solution of AuCl3. 3 Ag2Cl+ AUCl3 = 6AgCI +
Au. Fixing removes the unaffected AgCl, as in the negative, the
same substance being used. Describe the action. 2 AgCI + 3
Na2S203 = Ag2Na4(S203) + 2 NaCl. Both the positive and the
negative must be well washed after each process, particularly
after the last. The picture is then ready for mounting. In fine
portrait work both the negative and the positive are retouched.
This consists in removing blemishes with colored pencils or India
ink.
The negative--No. 1. Dissolve: sulphite soda crystals, 2 oz. (57
g) in 8 oz. (236 cc.) water (distilled); citric acid, 60 grains
(4 g) in 1/2 oz. (15 cc.) water; bromide ammonium, 25 grains (1
1/2 g) in 1/2 oz. water; pyrogallic acid, 1 oz. (28 g) in 3 oz.
(90 cc.) water. After dissolving, mix in the order named, and
filter. No. 2. Dissolve: sulphite soda, 2 oz. (57 g) in 4 oz.
(118 cc.) water; carbonate potash, 4 oz. (113 g) in 8 oz. (236
cc.) water. Dissolve separately, mix, and filter. To develop
plates, mix 1 dram (3 2/3 cc.) of No. 1 and 1 dram of No. 2 with
2 oz. (60 cc.) water. Cover the plate with the mixture, and leave
as long as the picture increases in distinctness. Remove, wash,
and put it into a saturated solution of alum for a minute or two,
then wash and put it into a half-saturated solution of hypo.
Leave till no white AgCl is seen through the back of the plate.
Wash it well.
The positive.--1. Dissolve 30 grains (2 g.) pure gold chloride in
15 oz. (450 cc.) water. This forms a stock solution. 2. Make a
saturated solution of borax. 3. Prepare a toning bath by adding
1/2 oz. (15 cc.) of the gold chloride solution and 1 oz. (30 cc.)
of the borax solution to 7 oz. (210 cc.) water. After printing
the picture, wash it in 3 or 4 waters, put it into the toning
bath, and leave it till considerably darker than desired; wash,
and put it for 15 minutes into a hypo solution that has been,
after saturation, diluted with 3 or 4 volumes of water. Then wash
repeatedly.
CHAPTER LII.
PLATINUM AND GOLD.
PLATINUM.
Examine platinum foil and wire.
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