An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
In 1895 Sir William Ramsay, who in the previous year had discovered an
inert gas, argon, in the atmosphere, identified a second inert gas
(obtained from minerals containing uranium and thorium) as helium
(ἥλιος, sun), an element previously revealed by spectrum analysis as a
constituent of the sun. In the same year Röntgen, while experimenting
with the rays that stream from the cathode in a vacuum tube, discovered
new rays (which he called X-rays) possessed of wonderful photographic
power. At the beginning of 1896 Henri Becquerel, experimenting on the
supposition, or hypothesis, that the emission of rays was associated
with phosphorescence, tested the photographic effects of a number of
phosphorescent substances. He exposed, among other compounds, crystals
of the double sulphate of uranium and potassium to sunlight and then
placed upon the crystals a photographic plate wrapped in two thicknesses
of heavy black paper. The outline of the phosphorescent substance was
developed on the plate. An image of a coin was obtained by placing it
between uranic salts and a photographic plate. Two or three days after
reporting this result Becquerel chanced (the sunlight at the time
seeming to him too intermittent for experimentation) to put away in the
same drawer, and in juxtaposition, a photographic plate and these
phosphorescent salts. To his surprise he obtained a clear image when the
plate was developed. He now assumed the existence of invisible rays
similar to X-rays. They proved capable of passing through sheets of
aluminum and of copper, and of discharging electrified bodies. Days
elapsed without any apparent diminution of the radiation. On the
supposition that the rays might resemble light he tried to refract,
reflect, and polarize them; but this hypothesis was by the experiments
of Rutherford, and of Becquerel himself, ultimately overthrown. In the
mean time the French scientist obtained radiations from metallic uranium
and from uranous salts. These, in contrast with the uranic salts, are
non-phosphorescent. Becquerel's original hypothesis was thus overthrown.
Radiation is a property inherent in uranium and independent both of
light and of phosphorescence.
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