An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
On April 13 and April 23 (1898) respectively Mme. Sklodowska Curie and
G. C. Schmidt published the results of their studies of the radiations
of the salts of thorium. Each of these studies was based on the work of
Becquerel. Mme. Curie examined at the same time the salts of uranium and
a number of uranium ores. Among the latter she made use of the composite
mineral pitchblende from the mines of Joachimsthal and elsewhere, and
found that the radiations from the natural ores are more active than
those from pure uranium. This discovery naturally led to further
investigation, on the assumption that pitchblende contains more than one
radioactive substance. Polonium, named by Mme. Curie in honor of her
native country, was the third radioactive element to be discovered. In
the chemical analysis of pitchblende made by Mme. Curie (assisted by M.
Curie) polonium was found associated with bismuth. Radium, also
discovered in this analysis of 1898, was associated with barium. Mme.
Curie succeeded in obtaining the pure chloride of radium and in
determining the atomic weight of the new element. There is (according to
Soddy) about one part of radium in five million parts of the best
pitchblende, but the new element is about one million times more
radioactive than uranium. It was calculated by M. Curie that the energy
of one gram of radium would suffice to lift a weight of five hundred
tons to a height of one mile. After discussing the bearing of the
discovery of radioactivity on the threatened exhaustion of the coal
supply Soddy writes enthusiastically: "But the recognition of the
boundless and inexhaustible energy of Nature (and the intellectual
gratification it affords) brightens the whole outlook of the twentieth
century." The element yields spontaneously radium emanation without any
apparent diminution of its own mass. In 1899 Debierne discovered, also
in the highly complex pitchblende, actinium, which has proved
considerably less radioactive than radium. During these investigations
M. and Mme. Curie, M. Becquerel, and those associated with them were
influenced by the hypothesis that radioactivity is an _atomic property_
of radioactive substances. This hypothesis came to definite expression
in 1899 and again in 1902 through Mme. Curie.
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