An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
In the latter year the physicist E. Rutherford and the chemist F. Soddy,
while investigating the radioactivity of thorium in the laboratories of
McGill University, Montreal, were forced to recognize that thorium
continuously gives rise to new kinds of radioactive matter differing
from itself in chemical properties, in stability, and in radiant energy.
They concurred in the view held by all the most prominent workers in
this subject, namely, that radioactivity is an atomic phenomenon. It is
not molecular decomposition. They declared that the radioactive
substances must be undergoing a spontaneous transformation. The daring
nature of this hypothesis and its likelihood to revolutionize physical
science is brought home to one by recalling that three decades
previously an eminent physicist had said that "though in the course of
ages catastrophes have occurred and may yet occur in the heavens, though
ancient systems may be dissolved and new systems evolved out of their
ruins, the molecules [atoms] out of which these systems are built--the
foundation stones of the material universe--remain unbroken and unworn."
In 1903 Rutherford and Soddy stated definitely their hypothesis,
generally known as the "Transformation Theory," that the atoms of
radioactive substances suffer spontaneous disintegration, a process
unaffected by great changes of temperature (or by physical or chemical
changes of any kind at the disposal of the experimenter) and giving rise
to new radioactive substances differing in chemical (and physical)
properties from the parent elements. The radiations consist of α
particles (atoms of helium minus two negative electrons), β particles,
or electrons (charges of negative electricity), and γ rays, of the
nature of Röntgen rays and light but of very much shorter wave length
and of very great penetrating power. It is by the energy inherent in the
atom of the radioactive substance that the radiations are ejected,
sometimes, in the case of the γ rays, with velocity sufficient to
penetrate two feet of lead. It is through these radiations that
spontaneous transformation takes place. After ten years of further
investigation Rutherford stated that this hypothesis affords a
satisfactory explanation of all radioactive phenomena, and gives unity
to what without it would seem disconnected facts. Besides accounting for
old experimental results it suggests new lines of work and even enables
one to predict the outcome of further investigation. It does not really
contradict, as some thought might be the case, the principle of the
conservation of energy. The atom, to be sure, can no longer be
considered the smallest unit of matter, as the mass of a β particle is
approximately one seventeen-hundredths that of an atom of hydrogen.
Still the new hypothesis is a modification and not a contradiction of
the atomic theory.
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