An Introductory Course of Quantitative Chemical Analysis: With Explanatory NotesTalbot, Henry Paul
Science
An Introductory Course of Quantitative Chemical Analysis: With Explanatory Notes
Talbot, Henry Paul
Chemistry, Analytic -- Quantitative
It is assumed that the Na^{+} ion, for example, differs from the
sodium atom in behavior because of the very considerable electrical
charge which it carries and which, as just stated, must, in an
electrically neutral solution, be balanced by a corresponding negative
charge on some other ion. When an electric current is passed through a
solution of an electrolyte the ions move with and convey the current,
and when the cations come into contact with the negatively charged
cathode they lose their charges, and the resulting electrically
neutral atoms (or radicals) are liberated as such, or else enter at
once into chemical reaction with the components of the solution.
Two ions of identically the same composition but with different
electrical charges may exhibit widely different properties. For
example, the ion MnO_{4}^{-} from permanganates yields a purple-red
solution and differs in its chemical behavior from the ion
MnO_{4}^{--} from manganates, the solutions of which are green.
The chemical changes upon which the procedures of analytical chemistry
depend are almost exclusively those in which the reacting substances
are electrolytes, and analytical chemistry is, therefore, essentially
the chemistry of the ions. The percentage dissociation of the same
electrolyte tends to increase with increasing dilution of its
solution, although not in direct proportion. The percentage
dissociation of different electrolytes in solutions of equivalent
concentrations (such, for example, as normal solutions) varies widely,
as is indicated in the following tables, in which approximate figures
are given for tenth-normal solutions at a temperature of about 18°C.
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