Processes for deliming pelt for chrome leather should also be chosen by
our guiding principle of hide substance conservation. Here again short
processes involving little change in swelling should be preferred. Now,
the ordinary bating and puering processes give (1) neutralization of
lime by organic acids combined with weak bases; (2) the solation of some
hide substance; and (3) a "pulling down" effect on the swollen pelt.
Now, neutralization is quite superfluous, as the acids of the chrome
liquor (one-bath or two-bath) can quite well accomplish this; the
solvent effect is undesirable altogether; and the "pulling down" effect
is also unnecessary if the goods are not plumped up. With any method of
liming, however, some plumping is obtained, and this creates a problem
of practical importance. In the huge quantities of pelt which go for
chrome upper leathers, a primary consideration is the soft, "kind," or
mellow feel of the grain in the finished leather. This is obtained only
by tanning the pelt when the grain at least is in a thoroughly deplumped
and inelastic condition. It is essential to delime not only so that the
alkaline plumping effect is completely removed, but also so that no acid
plumping effect succeeds it. The practical problem is to decide whether,
in any particular instance, dung puers and bates are necessary to obtain
this result. Bating is clearly not very desirable, on account of the
length of the process, during which hide substance would be lost
unnecessarily, and also because there will usually be a slight alkaline
swelling. Puering with dog-dung infusions is preferable; it is not such
a long process, the liquor is just acid to phenolphthalein, and the
action is more intense, and by puering for a short time only the loss of
hide may be confined to the grain and flesh only, whilst the desired
inelasticity of grain-pelt is soon obtained. Many large firms have
admittedly found themselves unable to dispense with puering, but others
have succeeded in substituting for it the use of non-swelling deliming
and lyotrope agents like ammonium chloride and boric acid. In all cases
it is futile to delime or puer the grain and then allow the goods to
stand until the centre lime has diffused outwards. The goods must pass
into the chrome liquors when in the correct condition. For heavy chrome
leather a surface deliming with boric acid is all that is necessary.
Even that is superfluous when the goods are to be pickled before
tanning.
Public-domain text, read in full here on John Shaqi.
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