=Types of One-bath Chrome Tannage.=--The one-bath process is simpler
than the two-bath process inasmuch as only one kind of liquor is
involved, viz. one in which the chromium is in the chromic state. Hence
the variants of the one-bath process consist mainly of variations in the
composition of this liquor. The chief point of variation is in the
readiness with which chromium hydrate is adsorbed. This is determined by
the extent to which the chromic salt is hydrolyzed to form the tanning
sol and free acid, and by the concentration and nature of this free acid
as well as of other substances. It is difficult unfortunately to express
these factors in terms which are comparable under general conditions.
Chromic salts are usually hydrolyzed to some extent, but this extent is
very different even in water, according to the nature of the acid
radical. The degree of hydrolysis is also largely affected by the extent
to which the solution has been "made basic" by the addition of alkalies.
By the neutralization of the free acid in this way there is further
hydrolysis, the extent of which is again influenced by the nature of the
acid radical involved and other dissolved substances, especially of
organic matters. Again, the hydrolysis is largely affected by the
concentration of the solution even when the proportions of the
ingredients are constant, and this is practically important on account
of the necessity for exhausting the chrome liquors economically. Nor is
the matter entirely one of degree of hydrolysis, for (as we have noted
in the preceding section) the electrical condition of the chroming sol
is of great importance owing to the operation of the valency rule and
the possibility of zones of non-precipitation. The alkaline, neutral or
acid condition of the goods when first introduced has also its influence
on all these points.
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