It will be readily understood, therefore, that there is some difficulty
in expressing the tanning power of a chrome liquor. As near as can be
yet said this is determined by (1) the concentration of the actual
tanning sol, and (2) its nearness to the isoelectric point. Now, these
points are not readily determined by analytical methods, and the best
that can yet be done is to determine the conditions which have large
influence upon these points. Thus the degree to which the liquor is
"made basic" by adding alkali is known, and can be expressed in formulæ
by assuming that the acid neutralized by this alkali is replaced in the
chrome salt by hydroxy groups. Chromic chloride, Cr{2}Cl{6}, with the
addition of soda to correspond to half the acid formed upon complete
hydrolysis, would be considered then to be a solution of the salt,
Cr{2}(OH){3}Cl{3}. This has given rise to the conception of the
"basicity" of a chrome liquor, which may be expressed in many ways, the
most common of which in practice is the number of grams SO{4} still
combined with 52 grams Cr. Thus the salt corresponding to the
composition Cr(OH)SO{4} is said to have a basicity of 96. The practical
importance of such determinations of basicity has been much exaggerated,
for they are but a rough guide to the degree of hydrolysis of the chrome
and to the extent to which the sol is positive. Thus if the chrome salt
be actually a sulphate, a liquor of basicity 96 has about the same
_practical_ value as a chloride liquor of basicity 72, and in each case
the figures are of little significance if many organic substances be
present. If, however, as is usual in practice, there be approximately
the same acid radicals throughout the tannage and about the same
relative proportion of organic matters or of inorganic salts, then these
determinations have some practical value for comparative purposes. The
determination is itself simple: a portion of liquor is titrated direct
with caustic soda. The titration is at boiling-point, and is continued
until a permanent pink is obtained with phenolphthalein. The amount of
SO{4} corresponding to the soda required is then relative to the amount
of Cr in the same volume of liquor. A chromium estimation is therefore
also necessary and is most readily done by evaporating a portion of
liquor to dryness, igniting the residue and oxidizing the chrome to
chromate by heating in a muffle furnace with magnesia and sodium
carbonate in equal parts, or fusing in a blowpipe with sodium and
potassium carbonates in equal parts. The oxidized residue is dissolved
in hydrochloric acid and titrated with thiosulphate as described for the
two-bath process.
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