For the manufacture of a permanent leather the essential requirements
are that the fibres of the hide or skins gel should be dried in a
separate condition, and that they should be coated by some waterproof or
insoluble material. Many substances fulfil the first but not the second
of these conditions. For example, the dehydration only may be
accomplished more or less by salt (as in curing hides), still better by
salt if a little mineral acid be used (as in pickling), and by other
salts such as potassium carbonate and ammonium sulphate, and dehydrating
agents such as alcohol. Such "temporary leathers," however, are not
water-resisting, as the second requirement has not been fulfilled, viz.
the coating of the fibres with some more or less waterproof material.
Thus if pelts dehydrated with alcohol be treated with an alcoholic
solution of stearic acid, the second condition is fulfilled and a
permanent leather is obtained.
Now, many tanning agents accomplish these two requirements only
imperfectly. As we have noted in the preceding section, the alum-tanned
leathers are not very water resisting, and much of the tannage will wash
out. Leathers made by the vegetable tannages usually contain some excess
of vegetable tanning matters which are soluble in and removed by water,
though much tannin can no longer be thus removed, owing to the mutual
precipitation of the oppositely charged tannin sol and hide gel. The
necessity for fulfilling the second requirement mentioned is one reason
for the practice of following these tannages by applications of oil, fat
or of both. In this way the isolated fibres are not only dried
separately, but are coated with a typical water-resisting material.
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