In the modern fat tannages drums are used to give the necessary
mechanical working to the goods. The raw hide leather produced in the
U.S.A. is made by drumming the nearly delimed goods with tallow and
neatsfoot oil. In this country the fat tannages have been typified by
the "Crown" and "Helvetia" leathers. The hides are thoroughly limed in
mellow limes, and after the beam work are delimed by drenching, scudded,
and sometimes fleshed again, and then coloured off in tan liquor. After
partial drying, they are drummed warm for some hours to ensure isolation
of the fibres. After further drying they are coated with the tanning
paste, which consists essentially of soft fats and flour to produce
partial emulsification. Equal parts of soft fats and of flour may be
used, to which may be added smaller proportions of degras, cod oil,
mutton tallow, salt, together with about 25 per cent. water. The goods
are coated with this mixture, drummed, and dried further, and this
routine repeated as often as necessary to fill the interstices
thoroughly with fat. The temperature in the drum may reach 95° F. In
finishing an attempt is made to stuff further with grease. The goods are
thoroughly set out, dried a little, and coated again, flesh and grain,
with a mixture of tallow, cod oil, glycerine and degras, and dried
further. The excess grease is slicked off and the goods again set out
and grained. They are then dried out.
REFERENCES.
Bennett, "Manufacture of Leather," pp. 245, 246 and 376.
Procter, "Principles of Leather Manufacture," p. 378.
SECTION III.--OIL TANNAGES
There are very obvious analogies between the fat tannages discussed in
Section II. and the oil tannages now to be dealt with, but there is
nevertheless a distinct departure in principle involved. In the oil
tannages the mechanical treatment is generally more vigorous, and the
"drying" process is conducted at a much higher temperature, with the
result that there is a vigorous oxidation of the oil. This results in
the formation of insoluble oxidation products which coat the fibre and
play an essential part in the production of a permanent leather. Pungent
vapours are evolved in the drying operations, amongst which is acrolein
and probably also other aldehydes, and it is thought by Procter that
these aldehydes also are essential tanning agents and typical of the
process (cf. Section IV.). Fahrion considers that the tanning action is
due solely to unsaturated fatty acids with more than one double linkage.
Garelli and Apostolo, however, believe that the tannage is due to a
coating of fatty acid whether saturated or not. These observers made
leather with stearic and palmatic acids in colloidal aqueous solution.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account