Gelatine has been crystallized by von Weimarn by evaporating a dilute
solution in aqueous alcohol whilst in a desiccator containing potassium
carbonate, the temperature being maintained at 60°-70° C. The carbonate
takes up water only, and the concentration of the alcohol therefore
slowly increases until the gelatine is no longer soluble. Gelatine is
usually found and known in the colloid state, however, and its behaviour
in this state only is of practical importance.
The fundamental idea of modern colloid chemistry is that colloids are
heterogeneous systems, usually two-phased, in which one phase is liquid
and the other phase either liquid or solid. The latter phase, which is
divided into small separate volumes, is known as the "disperse phase,"
whilst the other is the "continuous phase" or "dispersion medium." The
"dispersity" is the degree to which the reduction of the dimensions of
the disperse phase has been carried, and is best expressed numerically
in terms of "specific surface," _i.e._ surface area divided by volume,
but it is also often expressed as the thickness or diameter of a film or
particle. When the dispersity is not high, we have ordinary
"suspensions" and "emulsions," which with increasing dispersity merge
into the typical colloids. By analogy, colloids have been divided into
"suspensoids" and "emulsoids," when the disperse phase is solid and
liquid respectively. The classification, however, has not been found
satisfactory, for some systems in which the disperse phase is
undoubtedly liquid, exhibit characteristic properties of suspensoids,
and _vice versâ_. A more satisfactory division, therefore, is found in
the presence or absence of affinity between the two phases, the systems
being termed "lyophile" and "lyophobe" respectively. If water be the
continuous phase the terms "hydrophile" and "hydrophobe" are often used.
Broadly speaking, the lyophile colloids correspond to the emulsoids, and
the lyophobe colloids to the suspensoids. Gelatine is a typical
hydrophile colloid.
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