Another fundamental idea of colloid chemistry is that the great
extension of surface involved in a high dispersity causes the surface
energy to be no longer a negligible fraction of the total energy of the
system, and that the recent advances in knowledge respecting surface
phenomena may be called in to assist in the explanation of the special
properties of the colloid state. Particles which exhibit the Brownian
movement, about 10^(-5) cm. diameter, down to the limit of microscopic
visibility (10^(-3) cm.) are termed _microns_. Particles less than this,
but just visible in the ultra-microscope (5×10^(-7) cm.) are termed
_submicrons_. Particles still less, approximately 10^(-7) cm., have been
shown to exist, and are termed _amicrons_. The dimensions of molecules
such as may exist in true solutions are of the order of 10^(-8) cm. A
colloid sol may contain particles of various sizes. Thus a gelatine sol
(like other lyophile systems) contains chiefly amicrons, but submicrons
are also observable.
1. THE CONTINUOUS PHASE
Owing to the contractile force of surface tension, it is concluded that
the surface layer of a liquid is under very great pressure, much greater
than the bulk of the liquid. Any extension of the surface of the liquid
naturally causes a corresponding extension of the proportion of liquid
which is thus compressed. If in a beaker of water there be placed a
porous substance, such as animal charcoal, there is a great extension of
the surface of the water, and a corresponding increase in the amount of
compressed water. If instead there be substituted a large number of very
small particles of a substance, a still further increase in the amount
of compressed water is involved. As the specific surface of the
substance inserted is increased, and its amount, the proportion of
compressed and denser water increases also, until it is a practically
appreciable percentage of the total volume. It is clear also that the
extent of the zone of compression will be determined also by the nature
of the substance with which the water is in contact at its surface,
_i.e._ by the extent to which it is hydrophile, and this indeed may be
the more important factor.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account