As suggested above, it is probable that the extent of the zones of
compression is determined by another factor in addition to the great
development of surface. That factor is connected if not identical with
that power which makes the system lyophile, and is evidently connected
also with the solubility of the disperse phase, and may indeed be
electrochemical forces tending to form a series of hydrates, or at least
to cause an orientation or definite arrangements of the water molecules
in the zone of compression. This idea receives some support from the
hydrate theory of solution, and the zones of compression and orientation
are the colloid analogue of the hydrates supposed to exist in solutions
of electrolytes. The extension of such zones on cooling are then
analogous with the series of hydrates formed, for instance, by manganese
chloride with 2, 4, 6, 11, or 12 molecules of water when crystallized at
temperatures of 20°, 15°, -21°, -30°, and -48° C. respectively, the idea
being that the salts most hydrated in solution crystallize with most
water.
As the compression is the result of two factors, one of which depends
upon the nature of the disperse phase, we expect--and find--in other
lyophile systems a considerable variation in their power of gelation.
Some indeed, though very viscous, _e.g._ egg albumin, never quite set
like gelatine, and others (_e.g._ agar-agar) set to a stiff gel from a
much weaker sol than gelatine. When the zones of compression are large,
as in gelatine, the magnitude of the compressing force on the outermost
part of the zone is relatively small, and it is not surprising that time
is necessary for the victory of this force over the kinetic energy of
the water molecules. Hence we find a 5 per cent. jelly sets readily on
cooling, but its elasticity increases steadily for many hours after it
has set. This phenomenon, known as hysteresis, we should expect--and
find--to be much more marked in a case where the zone of compression is
unusually large (_e.g._ an agar gel). We should also expect--and
find--that hysteresis is more marked in a high-grade gelatine than in a
low-grade gelatine where both eventually form gels of equal elasticity.
We should expect too--and we find--that hysteresis is more prominent in
weak gels than in strong. These points are of obvious importance in
testing gelatine by its elasticity, _e.g._ the well-known "finger test."
There are also other facts and considerations which have an important
bearing upon the point under discussion. It is necessary ultimately to
regard true solutions of electrolytes and other bodies as heterogeneous,
though perhaps of a rather different order. From this point of view
molecules and ions existing in an aqueous solution will present a
surface and have associated zones of compression analogous with those
suggested for the minute particles of gelatine.
Public-domain text, read in full here on John Shaqi.
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