One consequence of this system is, that when a piece of gelatine
swells, there is a considerable enlargement in the zones of compression;
in other words, some, at least, of the imbibed water is compressed. Now
the compression of water means that work is done, and when gelatine
swells, therefore, we expect--and actually find--that heat is liberated
(5.7 cal per g. gel). Hence also by the Le Chatelier theorem, we
expect--and find--that gelatine swells best in _cold_ water. Further,
the compression of water involves a decrease in volume, and we therefore
expect--and actually find--that the volume of the swollen jelly is
appreciably less than the volume of gelatine plus the volume of water
imbibed.
Another consequence of such a compressed system is that a gelatine
jelly, even in water, will have a surface tension towards water just as
the water itself has such a tension to the water vapour above the
liquid. This interfacial tension of the jelly will of course have a
contractile effect, and will tend to resist swelling and to limit it as
far as it possibly can. This force, tending to contract the jelly and
resist imbibition is therefore one of the main influences at work in the
swelling of gelatine, and is one of the two principal factors which
determine the extent of the maximum swelling when equilibrium is
established. The force tending to resist swelling is, in the ultimate,
just surface tension. Its actual magnitude depends, of course, mainly
upon the extent of compression in the dispersion medium of the gel, and
will be a resultant which is a function of this compression. The
magnitude will thus vary with the average compression in the continuous
network of compressed water. It will be obvious that as the jelly swells
the power of resisting the swelling will decrease, and the interfacial
tension with the external water will tend to disappear. If the force
tending to swell were great enough the swelling would continue until the
zones of compression were no longer in contact and the gel would become
sol.
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