Before leaving this point, it is desirable to note the effect on the
swelling of gelatine of the extremes of this lyotrope influence.
Substances like iodides, thiocyanates and urea prevent a gelatine sol
from setting to a gel at all, and a piece of gelatine in such solutions
swells rapidly until it solates. On the other hand, sulphates,
tartrates, etc., make a stiffer gel on account of the enhanced
compression. Gelatine in such solutions may swell, but at a much slower
rate than in water and with a decreased maximum extent. A gelatine gel
may in such solutions not only fail to swell at all, but actually
contract and in some cases, indeed, be practically dehydrated. If a gel
be in a very concentrated solution of such a substance, it may be that
the lyotrope compression in the external solution is greater than the
compression in the dispersion medium of the gel; in which case the
surface tension effect is reversed, and the external solution tends to
increase in volume and the gel to contract. Hence we find that the
saturated solutions of such substances as ammonium sulphate and
potassium carbonate will dehydrate a gel almost completely, and will
also, by a similar action on pelt, make a kind of white leather. It is
important to remember this contractile effect of strong solutions of
salts, because it is very easy to confuse this effect with a similar
result produced in another manner, viz., by a reduction of the force
tending to swell.
2. THE DISPERSE PHASE
A very important feature of the colloid state is that the particles of
the disperse phase appear to possess an electric charge, and if this
charge be removed a colloid sol no longer remains such, but
precipitates, flocculates, coagulates, etc. As to the origin of this
charge several theories have been advanced, but the most generally
accepted is that it is a result of the adsorption of electrically
charged ions by the particles of the disperse phase. The enormous
specific surface possessed by this phase renders it particularly liable
to such adsorption. This view harmonizes well also with the general
behaviour, of colloid sols and gels, in endosmosis, kataphoresis,
precipitation, etc. According to this point of view the particles of the
disperse phase are surrounded by a surface layer in which these ions are
in much greater concentration than in the volume concentration of the
dispersion medium. The hydrion and hydroxyl ion are particularly liable
to such adsorption. In the case of a lyophile colloid, like gelatine,
the charge may be either positive or negative, according to the nature
of the predominant ions in the dispersion medium, and the amount of
adsorption is determined by the concentration of these ions in
accordance with the adsorption law.
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