Of course it is not likely that the simple figures selected for the
illustration of the argument are either relatively or absolutely
correct. Thus we know that the adsorption curve for hydrions and
hydroxylions are not likely to be quite identical, as assumed above. As
gelatin is primarily slightly positive, it is probable that the values
of _a_ and of _n_ for hydrion adsorption will be relatively slightly
greater. The relative values supposed, however, are near enough to
illustrate the contention that the type of the maximum volume curve can
be explained on this assumption of different adsorption isotherms for
each of the ions.
If the remarks on the compression of the continuous phase be recalled,
it will be obvious that in the present paragraphs we have been giving
the question of equilibrium-volume a rather one-sided consideration. The
volume of the gel when equilibrium is established may be determined in
type by the nett charge adsorbed by the disperse phase, but it will be
modified also by the lyotrope influence of the particular substance on
the continuous phase. When gelatine swells in solutions the influences
on both phases are always in operation, and either upon occasion may
become predominant. In the case of neutral organic substances, such as
cane-sugar, the lyotrope influence is the determining factor. In the
case of neutral salts the predominant influence is decided by the place
occupied by the salts in the lyotrope series. If at either end of the
series the lyotrope influence is uppermost and the effect of ionic
adsorptions is practically swamped. Thus sodium sulphate and sodium
iodide hinder and promote imbibition respectively as could be expected
from their strong lyotrope power. On the other hand, in the case of
sodium chloride, which has comparatively feeble lyotrope influence, the
relatively different adsorptions of its ions comes to the fore. With
acids and alkalies the relatively large adsorption of the hydrion and
hydroxylion causes this to be the predominant influence, but we must
concede the possibility that purely lyotrope influences may be at work
in some cases, and especially at the greater concentrations. Indeed, it
is sometimes a difficult problem to decide whether an increase or
decrease in swelling is due to lyotrope or adsorptive influence, but,
broadly speaking, we can expect strong lyotrope effects at either end of
the series and also at large concentrations, and we can expect strong
adsorptive effects in dilute solutions, in the middle of the lyotrope
series and in the case of alkalies and acids.
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