For much of the above explanation of the nature and behaviour of
gelatine, the author must himself take responsibility, and in this
section he has freely quoted from his own papers upon the subject (see
References). He claims that his view of a gelatine gel as involving a
network of compressed water, liable to modification by lyotrope
influence upon the continuous phase and by ionic adsorptions of the
disperse phase, is most in harmony with the recent advances in our
knowledge of colloids; that much of the theory is a necessary corollary
of those discoveries; and also that he has found this view to be a sound
guide in practice, both in tanning and in gelatine manufacture.
Many other theories have been advanced, but most are generalizations
over too limited a field, and from experiments with only a few
substances, and show little or no correlation with the wider facts of
colloid behaviour. That of Procter, for example, discards altogether the
idea of a two-phased structure of the gel as an "unproved and rather
gratuitous assumption," dismisses surface tension considerations as
"more complicated and less verified," and adsorption as "wholly
empirical," whilst it ignores lyotrope influence and the analogy with
agar gels completely. Procter's theory applies mainly to the swelling of
gelatine by acids, which swelling he considers to be due to the osmotic
pressure of the anion of a highly ionizable salt formed by the chemical
combination of the acid with gelatine. On this assumption, mathematical
considerations show that the electric charge on the gelatine is given by
the expression z = sqrt(4ex + e^2), where z = the amount of ion taken
up, x the concentration of the surrounding solution, and e the excess
concentration of diffusible ions in the jelly.
Public-domain text, read in full here on John Shaqi.
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