The property of gelatine and glue which is chiefly used in classifying
them into grades of different commercial value, is the strength of the
jelly obtained as compared with any arbitrary standard gelatine. An
enormous number of other physical tests have been devised, but none are
nearly so simple or so reliable. Gelatine is unfortunately very liable
to hydrolysis even by water, and long before any amido-acids, etc., have
appeared there is a change to a not greatly hydrolyzed product
(sometimes called [beta] gelatine) which has lost the power of setting
to an elastic gel. It is thus the lyophile nature which has been
altered, and the fall in elasticity corresponds to the fall in power of
compressing water, which is proportional to the concentration of [alpha]
gelatine. Now the elasticity of a gelatine gel varies as the square of
the concentration. Hence if one so arranges the concentrations of
standard and unknown samples that gels of equal elasticity are obtained,
the concentration of [alpha] gelatine is the same in both gels, and the
_relative_ amounts of [alpha] gelatine in the original samples are
inversely proportional to the weights used to give gels of equal
elasticity. The "strength" of a gelatine or glue is therefore usually
stated as the number of grams of a standard gelatine which will yield a
gel with elasticity equal to that from 100 grams of the gelatine or glue
being tested. Elasticity is matched by lightly pressing with the
finger-tips.
It is also possible to grade samples of gelatine and glue by the
estimation of "peptones," whose amount indicates the degree of
hydrolysis. Nitrogen is estimated by Kjeldahl's method in the sample and
in the precipitate obtained by saturating a solution with zinc sulphate.
The difference is calculated as peptones by multiplying by 5.33. Trotman
and Hackford say that the results are in the same sequence as those of
the finger test. The method, however, is much more laborious than the
"finger test."
Gelatine is also graded according to the results of bleaching and
clarifying, but with quite arbitrary standards, largely determined by
the fancy of the customer.
Chemical analyses, involving estimations of ash, lime, fat, acid, water,
insoluble matter, and poisonous metals, _e.g._ arsenic, copper, zinc and
lead, are of value for special cases according to the destiny of the
goods. Special physical tests, such as "breaking strain" and "foam
test," are also of some little value in special cases.
REFERENCES.
"The Chemistry of Colloids," W. W. Taylor. 1915.
"Handbook of Colloid Chemistry," W. Ostwald. 1919.
"Chemistry of Colloids," Zsigmondy and Spear. 1918.
"Introduction to the Chemistry and Physics of Colloids," E.
Hatschek.
"Surface Tension and Surface Energy," Willows and Hatschek.
"Chemistry of Colloids," V. Pöschl.
"Grundzüge d. Dispersoid Chemie," von Weimarn.
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