=Recovery and Purification of Grease.=--The degreasing operation, which
is applied usually to bones and to skin glue scutch, was once brought
about by steaming only, but is now accomplished with the assistance of
fat solvents, though in the latter case steaming together with
mechanical centrifugal force has proved sufficiently successful. On the
Continent carbon disulphide was once largely used as solvent, and in
this country benzene has been employed, but their low volatility and
high inflammability, as well as their expense, make both these
substances somewhat unsuitable, and it is now usual to make use of
petroleum oils, whether Scotch, American or Russian. A fraction which
boils about the same temperature as water is usually employed, and all
of it must be volatile under 280° F. Before the actual grease extraction
the bones should be sorted over and unsuitable substances (horns,
gravel, iron, etc.) removed. They are also usually put through a mill
and roughly crushed or broken. The actual grease extraction plant
consists of large copper vessels which will each take 5 tons of bones.
These extractors are arranged in sets so that the degreasing is
proceeding in some whilst the others are being emptied and recharged.
The doors for charging and emptying must be securely fastened. When the
extractor is charged the solvent is run in and heated by a steam coil
which eventually causes it to distil. After some hours the remainder,
which has dissolved much grease, is run off, and a fresh lot of solvent
is added and heated up. After four such extractions only about 1/4 per
cent. of grease remains in the bones. To remove the remainder of the
solvent high-pressure steam (80 lbs.) is blown through the bones. The
extractor is then opened and the degreased and somewhat dried bones are
mechanically conveyed to the cleansing mill. The grease solutions
obtained are subjected again to steam with a view to removing the
solvent and obtaining it for repeated use in this sense. The efficient
distillation and recovery of the solvent is indeed an essential element
in the success of the process.
The greases obtained, whether by the use of fat solvents or by skimming
off during extraction, or in any other way, are mixed together as is
appropriate to their origin and purity, and subjected to further
purification, the object of which is to remove gelatinous and albuminous
matters, and to decompose lime or soda soaps. The precise methods of
purification are, of course, dependent mainly upon the impurities known
to be present, but the readiest method is to give the grease further
steaming or boiling with water, and so effect by washing and by solvent
action the elimination of non-fatty matters. In many cases it is found
advantageous to employ mineral acids or oxidizing agents to assist the
process. The process may be repeated as often as is desired.
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