The recovered and purified greases are often of a high standard of
purity, and the best are quite fit for edible purposes. The large
extension of the margarine industry in this country has indeed caused a
larger proportion than ever of this bye-product to be so used. In some
cases it is found commercially advantageous to submit the grease to
action of the filter press, and so to separate it into solid and liquid
portions, the former containing a much larger proportion of stearin, and
the latter of olein. Much of the grease from the gelatine trade is also
found suitable for soap manufacture, and is therefore a valuable source
of glycerine.
=Other Raw Materials.=--Whilst hide pieces and fleshings, and animal
bones, comprise the principal raw material for the manufacture of
gelatine and glue, there are also minor sources of raw material which,
though often not suitable for gelatine manufacture, will yield a
satisfactory glue. Thus the skins, bladders and bones of fish form the
source of "fish glue." Sole skins, indeed, when deodorized by chlorine
and decolorized by animal charcoal, are made into gelatine. The bladders
of some fish (_e.g._ the sturgeon) are washed, purified and dried with
rolling to make "isinglass," a form of natural gelatine in which the
original fibrous structure is retained. There is a limited demand for
this material for clarifying purposes by brewers, wine merchants and
cooks.
Leather waste may sometimes be used to make a low-grade glue.
Vegetable-tanned leather offers much difficulty unless very lightly and
recently tanned. The tannage must be stripped by drumming with weak
alkalies, _e.g._ borax, sodium sulphite, or weak soda. Chrome leather
may be stripped easily and completely by Rochelle salt and other salts
of hydroxy acids (Procter and Wilson), and also by ammonia acetate,
oxalate and similar salts (Bennett), also by certain organic acids
(Lamb). Processes are patented by which chrome leather is digested with
lime to make glue, the chromium hydrate being insolubilized. Viscous and
tenacious substances are also obtained from some vegetable matters and
are called "glue."
REFERENCES.
"Glue and Glue Testing," S. Rideal, D.Sc., 2nd ed.; Skin Gelatine
and Glue, pp. 25-48; Bone Gelatine and Glue, pp. 59-66.
"Gelatine, Glue and their Allied Products," T. Lambert, pp. 11-52.
"Encyclopedie chimique," Fremy, tome x.
SECTION III.--EXTRACTION
The term "extraction" is applied to that essential process by which the
gelatinous matter from whatever raw material is used, is actually
dissolved in water and removed from the rest of the material. Extraction
is often termed "boiling" or "cooking." Whether one is treating hide
fleshings and pieces or whether one is dealing with raw or acidulated
bones, the general principles of extraction are much the same, and most
of this section is equally applicable to any class of material.
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