In the case of skin gelatine, also, sulphurous acid may fulfil a double
function, viz. that of deliming agent as well as of bleaching agent. In
such instance it is necessary to use excess of bleaching acid, some
acting as deliming material and the remainder as bleaching agent. As it
is desirable to get rid of the lime and soda salts, several changes of
liquor are given to the goods, possibly with intermediate washing. Here
again approximation to a counter-current system is of advantage, as the
employment of used bleach liquors for deliming purposes effects
considerable economy of sulphurous acid. Indeed, there need be no waste
acid at all.
Whether the material be for bone or skin gelatine, however, it will be
seen that the extraction is conducted in an acid condition and the
resulting sol is also acid. Most usually the decolorization and
filtration processes are also conducted with such an acid sol. From what
has been said (Section IV.) of the value of dibasic inorganic
acids as clarifying agents, it will be understood that the presence of
sulphurous acid at this stage is of great advantage in the production of
a clear and bright gelatine. Indeed, it is well known in trade circles
that sulphurous acid gelatines are usually of exceptional clarity and
brightness.
The disadvantage of sulphurous acid processes is also found in the same
fact that both sol, gel and cake are in an acid condition. To complete
the bleach it is sometimes necessary to add sulphurous acid to the sol
after extraction, or even after evaporation, but this is to be avoided
if possible. Usually the ideal attempted is that the bleaching action
should be as much as possible before extraction; the excess of
sulphurous acid is then washed off just before the extraction, as far as
practicable, and the rest is boiled off during extraction. The ideal is
practically never attained, for the acid is strongly adsorbed, and the
result is that the finished article is always an acid gelatine, and
sometimes indeed very decidedly such. The acid condition is
objectionable in the case of some forms of filter press on account of
the solvent action on the metals, and is objectionable in evaporation
for similar reasons. Acid gelatines are also objectionable for many
purposes for which gelatine is usually sold, and this limits the
commercial possibilities of the product thus obtained.
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