Sulphurous acid is itself, of course, a gas, and whilst the gas itself
has been used for treating the material (_e.g._ bones), it has been
found not only more convenient but also more effective to use an aqueous
solution. This is mainly because it is possible to attain a greater
adsorption in a liquor. Unfortunately, however, sulphurous acid is not a
very soluble gas, and although 8-10 per cent. solutions may be, with
great care, obtained, they are really supersaturated and readily yield
the gas, even with slight mechanical agitation. Solutions even of 2 to 3
per cent. strength are also liable to this, and the general experience
is that 1 to 2 per cent. solutions are most economical and convenient
for practical purposes. As the freight on weak solutions is prohibitive,
the manufacturer using sulphurous acid is faced with the necessity
either of purchasing cylinders of sulphur dioxide liquefied by pressure
or making the gas and solution himself. The former is the most
convenient course when only small amounts are required, but the latter
preferable for a gelatine factory of any size. Sulphurous acid is easily
manufactured by burning sulphur and leading the fumes by induced draught
up a scrubber down which water slowly trickles. Forced draught may also
be used, as in the Sachsenburg plant.
Of the other reducing agents which have been used, sodium hydrosulphite
(Na{2}SO{2}) deserves mention. It is a very powerful reducing agent,
and has been found most useful when employed as an assistant to
sulphurous acid. This reagent is usually added to the sol, after
evaporation and before gelation. It is sold as a white powder, usually
under trade names. Sometimes a mixture of bisulphite and powdered zinc
replaces it, but this is objectionable for pure food gelatines. Its use
also involves an impurity in the finished article, and a greater amount
of "inorganic ash."
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account