From the time the weak sol is decolorized and bleached, the finishing
processes consist essentially in the removal of water. This is now
usually done partly by evaporation of the sol, and partly by the
desiccation of the gel. There is an obvious elasticity in method, and
factory practice does actually vary considerably in the relative
proportions of these two alternatives. Some factories evaporate to a 20
per cent. sol, approximately, and rely upon drying sheds and lofts to
complete the desiccation: other factories evaporate up to a 55 per cent.
gelatine sol, and so can manage with less shed room. Something depends
upon local conditions, but the main issue is between the cost of steam
in evaporation and the cost of land and buildings required for sheds. On
the whole the modern tendency is to evaporate more, for this course has
the additional advantage of speed, involving both a quicker turnover and
less liability of putrefaction. Lower-grade products need relatively
greater evaporation to form a gel of equal rigidity.
After evaporation and bleaching, the concentrated sol is first cooled
rapidly until it has set to a stiff gel, then cut up into cakes
according to the size required, these being dried out on network frames
arranged in tiers, through which a draught of air is usually forced or
induced. This general description is of course applicable to many
factories with innumerable variations in detail, most of which
variations originate in local convenience and are unessential parts of
the manufacture.
An essential principle is that the cooling or gelation should be done
rapidly, not only to avoid putrefaction but also to avoid the action of
heat on the elasticity of the gel. A hot sol or gel is liable to
hydrolysis and loss of setting power, and should have its temperature
quickly reduced, but a warm sol or gel (say 100° F.) is most liable to
putrefaction, so that the cooling should be continued quickly. On the
other hand, the gel should not be frozen. For cooling purposes a copious
supply of cold water is most usually employed, but some factories have
installed refrigerators. These plants operate by the rapid evaporation
of liquefied gases such as carbon dioxide, sulphur dioxide, or ammonia,
so arranged as to cool a solution of common salt, which forms the
circulating liquor and is returned after use to the refrigerator. Where
such plants are used, it is natural that their use should be extended to
the drying sheds to cool the air entering in the height of summer. In
some factories the cooling is attained neither by cold water nor cooled
brine, but merely by cold air.
Public-domain text, read in full here on John Shaqi.
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