A better method is the "three-pit system." In this case each pack
receives three liquors and has (say) three days in each, first an "old
lime," then a "medium lime," and finally a "new lime." This system
ensures a greater regularity of treatment, and is deservedly the most
popular method for liming hides for sole leather. After being used once
as a "new lime," a liquor then becomes a "medium lime," and after being
thus used becomes the "old lime" which receives the green hides from the
soaks. The system involves the goods being shifted twice to another pit,
which is more laborious than reinsertion into the old pit, but if the
limeyard be arranged in "sets" or "rounds" of three pits, the shift is
usually only to the adjacent pit. One special advantage of this system
is that the top hides in one pit become the bottom hides in the next
pit, and _vice versâ_. Rounds of more than three pits are sometimes
used.
Many factories have now adopted systems in which there is no handling at
all. The hides are suspended in lime liquors which are agitated by
mechanical contrivances (_e.g._ Tilston-Melbourne process), or by jets
of compressed air (_e.g._ Forsare process). The goods are soaked and
limed "mellow to fresh" by changing the liquors by means of pumps, air
ejectors, etc. Thus the hides need no labour from first being inserted
until drawn for depilation.
In liming, the whole of the epidermis as well as the hair is loosened,
and is subsequently removed in depilation. The corium or true hide
substance becomes much more swollen by imbibation of water, and when
taken out of the new lime is "plumped" to very firm jelly. This plumping
is a matter of prime importance to the tanner. The coarser fibres are
thereby split up into the finer constituent fibrils, which fact assists
very materially in obtaining a quick and complete tannage, good weight,
and a firm leather. During the liming, the natural grease of the hide is
saponified or emulsified, which prepares for its removal in scudding.
Liming is thus a complex process: the hair is loosened, the hide is
plumped, and the grease is "killed." All these results may be hastened
by the use of other alkalies in addition, and most heavy leather yards
assist the liming by adding also sodium sulphide or caustic soda or
both. Sodium sulphide is a powerful depilatant, and will alone unhair
hides easily in strong solutions even in a few hours. As in solution it
forms caustic soda by hydrolysis, it possesses also the powerful
plumping and saponifying powers characteristic of the latter. The
addition of arsenic sulphide (As{2}S{2}) (realgar) to the lime when
slaking causes the presence of calcium sulphydrate in the lime liquors
thus made. This is also a powerful depilatant, but not much used for
heavy leather.
Public-domain text, read in full here on John Shaqi.
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