In addition to adsorption, there is another phenomenon of colloid
chemistry in operation, viz. the _mutual precipitation_ of the sols in
the liquid by the gels in the hide. In most sols the disperse phase is
electrically charged. The sol therefore possesses electric conductivity,
and migration occurs in the electric field to the cathode or anode
according to the nature of the charge. Oppositely charged sols
precipitate one another, the precipitate containing both colloids. The
maximum precipitation occurs when the + charge of one sol exactly equals
and neutralizes the - charge of the other. There is thus an electrical
equivalence; an amount of sol which is equivalent to a given amount of
the other. This is not a chemical equivalence, however, and the
precipitate is not a chemical compound in spite of its fairly constant
composition. The composition of the precipitate, indeed, is not quite
constant, for the optimum precipitation may not correspond exactly with
the electrical equivalence, being influenced by the number of particles
required, their size (dispersity), the rate of mixture, and the relative
concentrations of the sols. This mutual precipitation is exhibited by
emulsoids as well as suspensoids, but the charge (+ or -) on an emulsoid
is in many instances largely an accidental matter, being determined by
the medium in which it happens to be, its normal condition being
electrical neutrality. Gelatin and pelt are such emulsoids, and a
positively charged gelatin sol has been observed to precipitate a
negatively charged gelatin sol. It is thought, however, that gelatin is
primarily a positive sol. Pelt (whether delimed or not) is rapidly
acidified by the quickly penetrating and strongly adsorbed organic acids
of the old tan liquors and becomes positively charged before the tannins
are adsorbed. The positive charge increases with the acidity of the
liquor. Other emulsoids are not electrically neutral, but are
electrically charged and exhibit considerable conductivity. Into this
class fall the tannins, and in tanning it is thought that there is a
mutual precipitation of the negative tannin sol with the positive hide
gel, the precipitation of the negative sol being favoured by the acid
condition of the liquor. The effect of increasing acidity soon falls
off, however, as a saturation limit is soon reached. This mutual
precipitation of colloids in tanning is in reality but an extension of
the adsorption theory, which explains the predominant effect of H+,
and OH- on the electric charge by stating that these ions are more
readily adsorbed than other ions, and that as OH- is more readily
adsorbed than H+ most sols are negative to water.
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