Appletons' Popular Science Monthly, January 1900: Vol. 56, November, 1899 to April, 1900Various
Science
Appletons' Popular Science Monthly, January 1900: Vol. 56, November, 1899 to April, 1900
Various
Science -- Periodicals; Technology -- Periodicals
Although gun cotton, nitroglycerin, and their congeners can be and
usually are fired by detonation, there has within recent years been
a great number of compositions invented which, while formed from gun
cotton alone or mixtures of it with nitroglycerin, burn progressively
when ignited and are therefore available for use as propellants; and
since the products of their burning are almost wholly gaseous, they
produce but little or no smoke and are therefore called smokeless
powders. As upward of fifty-seven per cent of the products of the
burning of ordinary gunpowder are solids or easily compressed vapors,
this comparative smokelessness of the modern powders is a very
important characteristic, and when used in battle they seriously modify
our former accepted methods of handling troops. While this is the
feature of these powders which has attracted popular attention, a far
more important quality which they possess is the power to impart to
a projectile a much higher velocity than black powder does, without
exerting an undue pressure on the gun. A velocity of over twenty-four
hundred feet per second has been imparted to a one-hundred-pound
projectile with the powder that I have invented for our navy, while the
pressure on the gun was less than fifteen tons to the square inch.
[Illustration: TORPEDO PRACTICE. Bow discharge.]
Prior to my work in this field all the so-called smokeless powders were
mixtures of several ingredients, resembling gunpowder in this respect.
But, considering the precise and difficult work that was expected of
these high-powered powders and the difficulty which had always been
found in securing uniformity in mixtures, and that this difficulty had
become the more apparent as the gun became more highly developed, I
sought to produce a powder which should consist of a single chemical
substance in a state of chemical purity, and which could be formed into
grains of such form and size as were most suitable for the piece in
which the powder was to be used.
I succeeded in so treating cellulose nitrate of the highest degree of
nitration as to convert it into a mass like ivory and yet leave it
pure. In this indurated condition the gun cotton will burn freely, but
it has not been possible to detonate it even when closely confined and
exposed to the initial detonation of large masses of mercury fulminate.
[Illustration: TORPEDO PRACTICE ON THE CUSHING. Broadside discharge.]
I am happy to say that this principle has now been adopted by the
Russian Government, and by our navy in its specifications for smokeless
powder; but they have, I think unwisely, selected a cellulose nitrate
containing 12.5 per cent or less of nitrogen instead of that of the
highest nitration.
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