Artificial Light: Its Influence upon CivilizationLuckiesh, Matthew
History
Artificial Light: Its Influence upon Civilization
Luckiesh, Matthew
Electric lighting; Lighting -- History
Now to return to the peculiar property of rare-earth oxides--namely,
their unusual brilliance when heated in a flame--it is easy to
understand the reason for this. For example, when a number of substances
are heated to the same temperature they may radiate the same amount of
energy and still differ considerably in brightness. Many substances are
"selective" in their absorbing and radiating properties. One may radiate
more luminous energy and less infra-red energy, and for another the
reverse may be true. The former would appear brighter than the latter.
The scientific worker in light-production has been searching for such
"selective" radiators whose other properties are satisfactory. The
rare-earths possess the property of selectivity and are fortunately
highly refractory. Welsbach used these in his mantle, whose efficiency
is due partly to this selective property. Recent work indicates that
much higher efficiencies of light-production are still attainable by the
principles involved in the gas-mantle.
Turning again to flames, another interesting physical phenomenon is seen
on placing solutions of different chemical salts in the flame. For
example, if a piece of asbestos is soaked in sodium chloride (common
salt) and is placed in a Bunsen flame, the pale-blue flame suddenly
becomes luminous and of a yellow color. If this is repeated with other
salts, a characteristic color will be noted in each case. The yellow
flame is characteristic of sodium and if it is examined by means of a
spectroscope, a brilliant yellow line (in fact, a double line) will be
seen. This forms the basis of spectrum analysis as applied in chemistry.
Every element has its characteristic spectrum consisting usually of
lines, but the complexity varies with the elements. The spectra of
elements also exhibit lines in the ultra-violet region which may be
studied with a photographic plate, with a photo-electric cell, and by
other means. Their spectral lines or bands also extend into the
infra-red region and here they are studied by means of the bolometer or
other apparatus for detecting radiant energy by the heat which it
produces upon being absorbed. Spectrum analysis is far more sensitive
than the finest weighing balance, for if a grain of salt be dissolved in
a barrel of water and an asbestos strip be soaked in the water and held
in a Bunsen flame, the yellow color characteristic of sodium will be
detectable. A wonderful example of the possibilities of this method is
the discovery of helium in the sun before it was found on earth! Its
spectral lines were detected in the sun's spectrum and could not be
accounted for by any known element. However, it should be stated that
the spectrum of an element differs generally with the manner obtained.
The electric spark, the arc, the electric discharge in a vacuum tube,
and the flame are the means usually employed.
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