Auroræ: Their Characters and SpectraCapron, J. Rand
History
Auroræ: Their Characters and Spectra
Capron, J. Rand
Auroras
In the case of the Aurora, the question naturally arises whether the
oxygen of the air may be changed into ozone, perhaps also whether the
nitrogen may not be modified in some similar manner.
[Sidenote: Ozone destroyed by heat.]
The absorption spectra of oxygen, and of the same gas in its form of
ozone, may possibly differ; but this can hardly happen in the case of
incandescent oxygen, for ozone is at once destroyed by heat at 300°, and
slowly at 100°, and must be partially at least destroyed by the heat of
the discharge. If any lines were due to ozone in such a spectrum, we
should expect they would be weakened by heat and brightened by cold.
[Sidenote: Ozone in a large bell-receiver not manifested in spectrum.]
In the case of a continued discharge in a large exhausted bell-receiver,
the presence of ozone in considerable quantities was manifested to us by
its odour when the receiver was removed from the pump; but the spectrum
of the stream of light did not appear to differ from that in Geissler
tubes.
[Sidenote: Professor Dewar demonstrates that ozone is condensed oxygen.]
In a course of lectures at the Royal Institution in March 1878, on the
Chemistry of the Organic World, Prof. Dewar appears to have demonstrated,
by Prof. Andrews’ apparatus, that ozone is really condensed oxygen, and,
further, that during this condensation heat is absorbed, which is evolved
during the decomposition or re-expansion.
[Sidenote: Refers to the silent discharge between the atmosphere and the
earth.]
He also exhibited the oxidizing power of ozone in its action on mercury,
and commented on its similar action upon organic matter in forming
nitrates, and on its remarkable bleaching properties, but added there
was as yet no proof of its combining with free nitrogen. That peroxide
of hydrogen accompanies the formation of ozone by the slow combustion of
phosphorus, and that this peroxide acts with ozone in decomposing organic
bodies, though in an inexplicable manner, the Professor considered to be
proved. He also referred to the silent discharge probably perpetually
going on between the upper and lower strata of the atmosphere, and also
between these and the earth, accounting, as the Professor considered, for
some of the chemical actions whereby nitrogenous compounds are formed in
the soil.
[Sidenote: No spectrum of ozone obtained.]
As far as I am aware, no information as to a possible spectrum of ozone,
or a modification of the oxygen or other spectra by its presence, has, up
to the present time, been obtained[8].
[Sidenote: Suggestion to subject electric discharge to influence of cold.]
It has been suggested by Mr. Procter and myself that the electric
discharge in an exhausted moist tube, if subjected to a considerable
degree of cold, might produce a modification of the air-spectrum, perhaps
even a spectrum analogous to that of the Aurora.
For some further notes on this subject see Appendix D (Aurora and Ozone).
_Polarization of the Aurora Light._
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account