British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
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British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
It is a matter of astonishment to me that glass painters do not use a
ruby stain, which, with a little practice, can be managed quite as
successfully as the yellow silver one. It is true that it would be
impossible to fire the ruby and the silver stains together, and it
would not be at all convenient to fire the ruby stain at the first
firing of the painted glass. The method of staining ruby is as
follows: grind up carefully some black oxide of copper, mix it with
water (or with a small quantity of gum added), float it on the parts
to be coloured, place it in a kiln and heat it. Black oxide of copper,
when mixed with glass and melted in a glass-pot, makes the glass
green; suboxide of copper, which contains less oxygen than the black
oxide, when treated in the same way, makes it red. Now, if it can be
reduced to the lower oxide of copper, while the black oxide of copper
on the surface of the glass is heated, it will then colour the glass
red. The best way of reducing the black oxide, is to connect the
muffle with a gas-supply pipe, and allow coal gas to pass during the
whole time that the heating process goes on. The action of the gas,
which contains hydrogen and carbon, is to take away oxygen from the
black oxide of copper, when it is at a high temperature; and, as soon
as sufficient is taken away by the hydrogen to reduce the black oxide
to the state of suboxide, it stains the glass red. It does not matter
if the reducing action be continued longer, so that the oxide of
copper be reduced to the metallic state; for at that temperature, the
stain produced by the red oxide of copper is not removed by the
continued action of hydrogen gas. The employment of this process would
certainly enable artists who paint in the later styles of glass
painting, to very much enrich their draperies, and to produce, more
easily, effects which now can only be obtained by a complicated system
of lead-work.
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