British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
_Annealing and Devitrification._--As the word "annealing" has been
often used in this article, it will be well to explain what is its
action. If a piece of molten glass be dropped into water, it will
assume an oblong shape, the lower end of which will be round, while
the other will taper off into a fine point. These drops, which have
received the name of Prince Rupert's drops, look like pieces of
ordinary glass, and if the small end of one of them be broken off, a
sort of explosion takes place, and the whole mass flies into a
thousand minute pieces, some of which will be found to have been
driven to a considerable distance. Here then it appears, that when the
skin, which is perfect and entire in the Rupert drop, is broken, the
bond which held together the constituent particles is broken also, and
so they are acted on by a repellent force, and fly away from one
another. If hot water be poured into a thick common tumbler, it very
generally cracks it: but if the tumbler be thin and of better
manufacture, it will bear almost boiling water without cracking. In
the first case it has been badly annealed; and besides this, glass
being a bad conductor of heat, from its thickness, the heat imparted
by the hot water expands the inner surface, while the outer coating,
not being warmed, does not expand, and, retaining its original form,
is burst. If, however, a tumbler be thick and properly annealed, there
is not so much danger of its breaking, when a portion of it is exposed
to a considerable rise of temperature. In the case of the Rupert
drops, they are not annealed at all, and so there is no cohesive bond
between the particles, such as there would be if they were properly
annealed, that is, if, instead of being cooled suddenly from the
molten state, they were allowed to cool in a heated chamber very
slowly. After glass has been heated, the particles of which it is
composed take a long time to rearrange themselves, so that in the
manufacture of thermometers, it is necessary, after sealing up the
bulb and tube which contain the mercury, to allow them to remain for a
long time; otherwise the pressure of the air on the outside of the
bulb, not being supported by any air on the inside, causes the
particles of glass to become more compact, and thus renders the
capacity of the thermometer bulb and tube smaller than it was, when
the thermometer was first sealed. It seems that the process of
annealing glass gives time for the particles to arrange themselves in
such a way, that when the glass is cold, it will not be so liable to
fracture from sudden changes of temperature.
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