British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
There is also a very ingenious way of making silicate of soda,
discovered by Mr. Gossage, and performed as follows: common salt is
heated to a high temperature and volatilized, and in this condition is
brought into contact with steam also at a high temperature, when a
double decomposition takes place. Steam is composed of oxygen and
hydrogen; common salt, of sodium and chlorine. The chlorine of the
common salt unites with the hydrogen of the steam, and the oxygen of
the steam with the sodium, so that hydrochloric acid and oxide of
sodium are formed. Now, if these two substances at this high
temperature were allowed to cool together, the action would be
reversed, and the re-formation of steam and chloride of sodium would
be the result; but in the strong chamber lined with fire-clay, in
which these vapours are brought into contact, silica is placed in the
form of sand made up into masses, and when the oxide of sodium is
formed, it unites with the sand to make silicate of soda, and thus is
removed from the action of the hydrochloric acid, not entirely, but
sufficiently to produce a large yield of silicate of soda.
The properties of silicate of soda, as applied to the arts, are
somewhat different from those of silicate of potash, so that one
cannot always be substituted for the other. Both these substances are,
when in solution and concentrated, thick and viscid, and have the
property of causing paper, wood, &c., to adhere when applied as a gum
or glue, and hence have been called "mineral glue." In a dilute state
they can be used for coating stone, brick, or cement, and have the
power of rendering them for a time waterproof, or nearly so, and of
preventing the action of atmospheric influences, which too often
produce the decay of some of the softer stones used for building as
well as for cement. It has already been stated, that when carbonic
acid is passed through a solution of silicate of soda, silica will be
precipitated. Now, inasmuch as there is carbonic acid in atmospheric
air, when these solutions are applied to the surfaces of a building,
they will be acted upon slowly by the acid, and silica will be
precipitated in the pores of the material to which the silicates are
applied. But this operation is extremely slow, and, before it can be
thoroughly completed, the silicates, being soluble, will get in part
dissolved out by rain and moisture, and it is therefore advisable to
use with them some material which will, by a double decomposition,
form a silicate insoluble in water. The silicate, however, which is
formed, should have cohesion amongst its particles, so that it will
not only adhere to the stone itself, but its own particles will adhere
to one another when it gets dry. Various methods have been tried to
cause this insoluble substance to be formed upon the surface of
stones, so as to fill up its pores and to make a protecting cover for
it; but most of them have signally failed, because the new silicate
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