British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
produced by double decomposition has not had the necessary coherence
amongst its particles. If a solution of chloride of calcium be added
to one of silicate of soda, a silicate of calcium will be
precipitated, and it was therefore thought, that by applying to a
stone successive washes of silicate of soda and chloride of calcium,
an insoluble silicate of calcium would be produced in the pores and on
its surface. It is true that such a silicate is precipitated, and
that, if the silicate employed be in excess of the chloride of
calcium, the particles will be glued together by the adhesive powers
of this silicate when it dries; but then the action of moisture upon
it is to cause it to run down the surface of the building, and set
free the particles of silicate of calcium which it held in
combination. Other processes of the same kind have been tried, and
with similar results; one great difficulty in the way of the success
of this method of applying silicates being that, from the peculiar
colloidal or gluey nature of the silicate, it does not penetrate to
any considerable depth into the stone, and, if laid on first, prevents
the penetration, as far even as it has itself gone, of the solution of
chloride of calcium. If the chloride of calcium be used before the
silicate, it will penetrate farther than the solution of silicate is
able to reach, so that it is impossible to obtain, even supposing the
substance to be used in equivalent proportions, a complete
decomposition of the one by the other.
The great object to be attained in the preservation of stone by
any silicious process, is to use _one_ solution possessing the
substances which, when the water has evaporated, will form a
perfectly coherent mass for the protection of the stone surface. The
depth of penetration, if it is sufficient to protect the outside of
the stone from the disintegrating action of the atmosphere, need not
be carried much more than one-sixteenth of an inch below the surface,
for when old stones which have long been in positions in buildings,
and which have not decayed at all, are examined, it will be found
that they are covered with an extremely thin film of a hard
substance, not thicker than a sheet of writing paper, which has for
ages protected and preserved them from decay. This film is produced
by a determination from the inside to the outside of the stone of a
silicious water, which existed in it in the quarry, and which, when
the stone was placed in the building, gradually came to the surface,
the water evaporating and leaving behind it a thin film of silica, or
of a nitrate--most likely the latter.
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