Buffon's Natural History. Volume 10 (of 10): Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &cBuffon, Georges Louis Leclerc, comte de
History
Buffon's Natural History. Volume 10 (of 10): Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &c
Buffon, Georges Louis Leclerc, comte de
Natural history
Being at Dijon the summer of 1773, the Academy of Sciences and Belles
Letters, of which I have the honour to be a member, expressed a desire
of hearing my observations on platina; and having complied, M. de
Morveau resolved to make some experiments on this mineral; for which
purpose I gave him a portion of that which I had attracted by the
loadstone, and also some which I had found insensible to magnetism,
requesting him to expose it to the strongest fire he could possibly
make. Some time after, he sent me the following experiments, which he
was pleased to subjoin to mine.
"Monsieur the Comte de Buffon, in a journey to Dijon, in the summer
of 1773, having caused me to remark in half a drachm of platina,
which M. de Baume had sent him in 1768, grains in form of buttons,
others flatter, and some black and scaly; and having separated by the
loadstone those which are attractable from those which appeared not so,
I tried to form Prussian blue with both. I sprinkled the fuming nitrous
acid on the non-attractable parts, which weighed 2-1/2 grains. Six
hours after I put distilled water on the acid, and sprinkled alkaline
liquor, saturated with a colouring matter; however there was not a
single atom of blue, the platina had only a little more brightness.
I alike sprinkled the fuming acid on the remaining platina, part of
which was attractable, the same Prussian alkali precipitated a blue
feculency, which covered the bottom of a pretty large bason. The
platina, after this operation, shewed like the first. I washed and
dried it, and found it had not lost 1/4 of a grain, or 1/138 part;
having examined it in this state I perceived a grain of beautiful
yellow, which was pure gold.
"M. de Fourcy had lately told the world, that the dissolution of gold
was thrown down in a blue precipitate by the Prussian alkali, and
had placed this circumstance in a table of affinity; I was tempted
to repeat this experiment, and sprinkled, in consequence, the
phlogisticated alkaline liquor in the dissolution of gold, but the
colour of this dissolution did not change, which made me suspect that
the dissolution of gold made use of by M. de Fourcy might possibly not
have been so pure.
"At the same time the Comte de Buffon having given me a sufficient
quantity of platina to make further assays, I undertook to separate it
from all foreign bodies by a good front; and I have here subjoined the
processes and their results.
EXPERIMENTS.
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