The first product obtained consist in the addition of one
acetylene to the arsenic trichloride molecule, and, chemically, is
chlorovinyldichloroarsine, CHCl: CH·AsCl₂, a colorless or faintly
yellow liquid, boiling at 93° at a pressure of 26 mm. A small quantity,
even in very dilute solution, applied to the skin causes painful
blistering, its virulence in this respect approaching that of mustard
gas. It is more valuable than mustard gas, however, in that it is
absorbed through the skin, and as stated on page 23, three drops,
placed on the abdomen of a rat, will cause death in from one to three
hours. It is also a very powerful respiratory irritant, the mucous
membrane of the nose being attacked and violent sneezing induced. More
prolonged exposure leads to severe pain in the throat and chest.
The second fraction (β, β′-dichlorodivinylchloroarsine) is a product
resulting from the addition of two acetylene molecules to one arsenic
trichloride, and boils at 130° to 133° at 26 mm. It is much less
powerful as a vesicant than chlorovinyldichloroarsine, but its irritant
properties on the respiratory system are much more intense.
The third fraction, β, β′, β″-trichlorotrivinylarsine, (CHCl: CH)₃As,
is a colorless liquid, boiling at 151° to 155° at 28 mm., which
solidifies at 3° to 4°. It is neither a strong vesicating agent nor a
powerful respiratory irritant. At the same time, its odor is pungent
and most unpleasant and it induces violent sneezing.
CHAPTER XI
CARBON MONOXIDE
Carbon monoxide, because of its cheapness, accessibility and ease of
manufacture, has been frequently considered as a possible war gas.
Actually, it appears never to have been used intentionally for such
purposes. There are several reasons for this. First, its temperature of
liquefaction at atmospheric pressure is -139° C. This means too high a
pressure in the bomb or shell at ordinary temperatures. Secondly, the
weight of carbon monoxide is only slightly less than that of air, which
keeps it from rolling into depressions, dugouts and trenches, as in
the case of ordinary gases, and also permits of its rather rapid rise
and dissipation into the surrounding atmosphere. A third reason is its
comparatively low toxic value, which is only about one-fifth that of
phosgene. However, as it can be breathed without any discomfort, and as
it has some delay action, its lack of poisonous properties would not
seriously militate against its use were it not for the other reasons
given.
Public-domain text, read in full here on John Shaqi.
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