It is, nevertheless, a source of serious danger both in marine and
land warfare. Defective ventilation in the boiler rooms of ships
and fires below decks, both in and out of action, are especially
dangerous because of the carbon monoxide which is produced. In one of
the naval engagements between the Germans and the English, defective
high explosive shell, after penetrating into enclosed portions of the
ship, evolved large quantities of carbon monoxide and thus killed some
hundreds of men. On shore, machine gun fire in enclosed spaces, such
as pill boxes, and in tanks, liberates relatively large quantities of
carbon monoxide. Similarly, in mining and sapping work, the carbon
monoxide liberated by the detonation of high explosives constitutes one
of the most serious of the difficulties connected with this work and
necessitated elaborate equipment and extensive military training in
mine rescue work.
The removal of carbon monoxide from the air is difficult because of its
physical and chemical properties. Its low boiling point and critical
temperature makes adequate adsorption at ordinary temperatures by the
use of an active absorbent out of the question. Its known insolubility
in all solvents similarly precludes its removal by physical absorption.
After extensive investigation two absorbents have been found.[24] The
first of these consists in a mixture of iodine pentoxide and fuming
sulfuric acid, with pumice stone as a carrier. Using a layer 10 cm.
deep and passing a 1 per cent carbon monoxide air mixture at the rate
of 500 cc. per minute per sq. cm. cross section, a 100%-90% removal
of the gas could be secured for two hours at room temperature and
almost as long at 0° C. The reaction is not instantaneous, and a brief
induction period always occurs. This may be reduced to a minimum by the
addition of a little iodine to the original mixture.
[Footnote 24: Complete details of this work may be found in _J. Ind.
Eng. Chem._, =12=, 213 (1920).]
The sulfur trioxide given off is very irritating to the lungs, but
by the use of a layer of active charcoal beyond the carbon monoxide
absorbent, this disadvantage was almost completely eliminated. However,
sulfur dioxide is slowly formed as a result of this adsorption and
after prolonged standing or long-continued use of the canister at a
high rate of gas flow gives serious trouble.
Considerable heat is given off in the reaction and a cooling attachment
was required. The most satisfactory device was a metal box filled
with fused sodium thiosulfate pentahydrate, which absorbed a very
considerable amount of the heat.
Still a further disadvantage was the fact that the adsorbents became
spent by use, even in the absence of carbon monoxide, since it absorbed
enough moisture from the air of average humidity in several hours, to
destroy its activity.
The difficulties mentioned were so troublesome that this absorbent was
finally supplanted by the more satisfactory oxide absorbent described
below.
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