“It is obvious, therefore, that conditions of activation must be so
chosen and regulated as to oxidize the hydrocarbons rapidly and the
primary carbon slowly. Such a differential oxidation is not easy
to secure since the hydrocarbons involved have a very low hydrogen
content, and are not much more easily oxidized than the primary
carbon itself. Furthermore, most of the hydrocarbons to be removed
are shut up in the interior of the granule. On the one hand, a high
enough temperature must be maintained to oxidize the hydrocarbons
with reasonable speed; on the other hand, too high a temperature must
not be employed, else the primary carbon will be unduly consumed. The
permissible range is a relatively narrow one, only about 50 to 75°.
The location of the optimum activating temperature depends upon the
oxidizing agent employed and upon other variables as well; for air, it
has been found to lie somewhere between 350 and 450°, and for steam
between 800 and 1000°.
“The air activation process has the advantage of operating at a
conveniently low temperature. It has the disadvantage, that local
heating and an excessive consumption of primary carbon occur, so that a
drop in volume activity results from that cause before the hydrocarbons
have been completely eliminated. As a consequence, charcoal of the
highest activity cannot be obtained by the air activation process.”
The steam activation process has the disadvantage that it operates
at so high a temperature that the regulation of temperature becomes
difficult and other technical difficulties are introduced. It has the
advantage that local heating is eliminated. The hydrocarbons can,
therefore, be largely removed without a disproportionate consumption of
primary carbon. This permits the production of a very active charcoal.
It has the further advantage that it worked well with all kinds of
charcoal. Inferior material, when treated with steam, gave charcoal
nearly as good as the best steam-treated cocoanut charcoal. Because of
the shortage of cocoanut, this was a very important consideration.
[Illustration: FIG. 68.—Section of Raw Cocoanut Shell. Magnified 146½
diameters.]
The air, steam and also carbon dioxide-steam activation processes have
all been employed on a large scale by the Chemical Warfare Service for
the manufacture of gas mask carbon.
[Illustration: FIG. 69.—Section of Carbonized Cocoanut Charcoal.
Magnified 146½ Diameters.]
[Illustration: FIG. 70.—Two-Minute Charcoal not Activated. Magnified
732 Diameters.]
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