“Under such treatment the charcoal is given a high
degree of activation without the usual accompanying
high losses. Seemingly the oxidizing medium used,
together with the operating conditions, produce a
deep penetration of the charcoal particles without
increasing the extensive surface combustion experienced
in the steam activators. The capacity of such a type
furnace is limited only by the size of the installation.
“The advantages of this type furnace may be tabulated as follows:
1—High quality of product.
2—Small weight and volume losses.
3—Large capacity per unit.
4—Minimum initial cost and maintenance of installation.
5—Simplicity and cheapness of operation.
6—Adaptability to activation of all carbon materials.
7—Availability of furnaces of this general type already constructed.”
SUBSTITUTES FOR NUT CHARCOAL
The first experiments were made with a special anthracite coal
(non-laminated and having conchoidal fracture). This had a life of 560
minutes as against 360 minutes for air treated cocoanut charcoal and
800-900 minutes for steam-treated charcoal.
When the Gas Defense Service tried to activate anthracite on a large
scale in vertical gas retorts at Derby, Connecticut, the attempt was
a failure. They carbonized at 900° and then turned on the steam with
the result that the steam-treated coal had a slightly greater density
than the untreated, which was wrong, and had a shiny appearance in
parts with roughened deposits in other parts. When the hydrocarbons
are decomposed at high temperatures, the resulting carbon is somewhat
graphitic, is itself inactive, is not readily oxidized, and impairs
or prevents the activation of the normal carbon upon which it is
deposited. This discovery made it possible to treat anthracite
successfully. The conditions must be such as to minimize high
temperature cracking, to carry off or oxidize the hydrocarbons as fast
as formed, and especially to prevent the gases from cooler portions of
the treater coming in contact with carbon at a much higher temperature.
With these facts in mind, a plant was built at Springfield which
produced 10 tons a day of 150-300 minute charcoal from raw anthracite.
This was one-third of the total production at that time and was mixed
with the nut charcoal made at Astoria, thereby preventing an absolute
shortage of canister-filling material in October, 1918.
It was next shown that the cocoanut charcoal fines resulting from
grinding and screening losses and amounting to 50 per cent of the
product, could be very finely ground, mixed with a binder, and baked
like ordinary carbon products. By avoiding gas-treating in the bake,
the resulting charcoal is nearly as good as that from the original
shell. A recovery plant for treating the cocoanut fines was built at
Astoria. The product was called “Coalite.”
Public-domain text, read in full here on John Shaqi.
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