The great advantage of cocoanut shell as a source of charcoal is that
it is very dense and consequently it is possible to convert it into a
mass having a large number of fine pores, whereas a less dense wood,
like cedar, will necessarily give more larger pores, which are of
relatively little value. The cocoanut charcoal is also pretty resistant
to oxidation which seems to make selective oxidation a more simple
matter. By briquetting different woods, it is possible to make charcoal
from them which is nearly equal to that from cocoanut shell.
By heating lamp-black with sulfur and briquetting, it was possible to
make a charcoal having approximately the same service time as cocoanut
charcoal. A charcoal was made by emulsifying carbon black with soft
pitch, which gave the equivalent of 400 minutes against chloropicrin
before it had been steam-treated. This looked so good that the plans
were drawn for making a thousand pounds or more of this product at
Washington to give it a thorough test. This was not done on account
of the cessation of all research work. The possible advantage of this
product was the more uniform distribution of binder.
Instead of steam-treating anthracite coal direct, it was also
pulverized, mixed with a binder, and baked into rods which were then
ground and activated with steam. The resulting material, which was
known as Carbonite, had somewhat less activity than the lamp-black
mixes but was very much cheaper. A plant was built to bake 40 tons a
day of this material, which would yield 10 tons a day of active carbon
after allowing for grinding losses and steam treatment. The plant was
guaranteed to furnish an absorbent having a life of 600 minutes against
chloropicrin.
GERMAN CHARCOAL
After the Armistice was signed, Chaney took up the question of how
the Germans made their charcoal. The German charcoal was made from
coniferous wood and was reported to be as good as ours, in spite of
the fact that they were using inferior materials. Inside of a month
Chaney had found out how the German charcoal was made, had duplicated
their material, and had shown that it was nothing like as good as
our charcoal. The Germans impregnated the wood with zinc chloride,
carbonized at red heat, and washed out most of the zinc chloride. When
this zinc chloride was found in the German charcoal, it was assumed
that it had been added after the charcoal had been made. It was
therefore dissolved out with hydrochloric acid, thereby improving the
charcoal against chloropicrin. The German charcoal was then tested as
it stood, including the fines, against American charcoal, 8 to 14 mesh.
The most serious error, however, was in testing only against a high
concentration of chloropicrin. The German charcoal contains relatively
coarse pores which condense gases at high concentrations very well but
which do not absorb gases strongly at low concentrations. The result
was that the German charcoal was rated as being four or five times as
good as it really was.
Public-domain text, read in full here on John Shaqi.
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