In discussing the work one can very well start with the Offense
Section. This Section had two aims in view always, to develop methods
of making the gases used by the Germans more economically than they
were making them, and to develop better gases if possible. When we
entered the war, chlorine, phosgene and chloropicrin were the lethal
gases used, while bromoacetone and xylyl bromide were the lachrymators.
It was not a difficult matter to prepare these. But the introduction
of mustard gas in the summer of 1917 and of diphenylchloroarsine in
the autumn of the same year, not only made our chemists ponder over
a manufacturing method, but also so revised our notions of warfare
that the possibility of using other substances created the need for
extensive research. The development of bromobenzylcyanide by the French
likewise opened a new field among lachrymatory substances.
Colored rockets and smokes were developed for the Navy and Army.
The smoke box was also studied but the work was taken over by the
Pyrotechnic Section.
A large amount of pure inorganic research on arsine and arsenides,
fluorine, hydrofluoric acid and fluorides, cyanides, cyanogen sulfide
and nitrogen tetroxide was carried out, sometimes successfully and at
other times with little or no success.
The Analytical Section not only carried out all routine analyses but
developed methods for many new gases.
The Offense Section worked in very close contact with the Small Scale
Manufacturing Section (Chemical Production Section). Often it happened
that a method, apparently successful in the laboratory, was of no
value in the plant. Small scale plants were developed for mustard gas,
hydrocyanic acid, cyanogen chloride, arsenic trichloride, arsenic
trifluoride, magnesium arsenide, superpalite and bromobenzylcyanide.
The Chemical Defense Section, organized January, 1918, was occupied
with problems relating to protection, such as charcoal, soda-lime, and
special absorbents, eyepieces, smoke filters, efficiency of absorbents,
and special work with mustard gas.
Charcoal demanded extensive research. Raw materials required a
world-wide search, carbonizing methods had to be developed, and
impregnating agents were thoroughly studied. This story is told in
Chapter XIII.
Soda-lime was likewise a difficult problem. Starting with the British
formula, the influence of the various factors was studied and a balance
between a number of desirable qualities, absorptive activity, capacity,
hardness, resistance to abrasion, chemical stability, etc., obtained.
The final product consisted of a mixture of lime, cement, kieselguhr,
sodium permanganate and sodium hydroxide.
Public-domain text, read in full here on John Shaqi.
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