The living matter of the body is composed of a variety of substances,
of which protoplasm may be taken as typical. This is highly complex,
and while it can be imitated by the chemist, its living properties have
not been reproduced. (See my book on “Life: Its Origin and Nature,” in
the present series.) The various secretions and excretions of the body
have been studied exhaustively by physiological chemists. _Plants_ have
also been studied minutely from a similar point-of-view.
A number of important discoveries have resulted from this work,
however, and nearly all the essential animal and vegetable substances
are at present accessible to artificial synthesis from their very
elements. Even protein matter seems to have lost much of its mystery
since we have learned from Emil Fischer’s work that amino-acids can
be combined in the same way as they occur in protein. Compounds of
Amino-acids can be obtained, which show all the main reactions of
protein substances. Emil Fischer, of Berlin, was the same chemist
who, in 1886, discovered how to prepare grape-sugar from glycerine.
A considerable number of plant alkaloids have also been artificially
prepared in the course of the last five or six decades. The most
important coloring matters of plants--for instance, alizarin and
indigotin,--are no longer extracted from plants for technical
purposes, but are accessible from the products of coal-tar.
CATALYSIS
We now come to a remarkable series of chemical phenomena, which have
been much studied during the past century, and which have a bearing
upon both organic and inorganic chemistry. More than a century ago,
it was discovered that certain chemical substances, which will not
normally combine with one another, can be made to do so, if another
substance is brought into contact with them. This third substance does
not in any way enter into the combination, or share in the reaction;
its mere presence seems to bring it about. Thus, oxygen and hydrogen
may be mixed together; but if a small amount of “platinum black” be
introduced, an explosion of the gases at once occurs. Hydroperoxide
is rapidly split into oxygen and water when in contact with “platinum
black,” etc. These contact-effects are very curious, and have engaged
the attention of chemists for a long time. Berzelius is responsible for
the term now generally used--_catalysis_. We now speak of catalytic
power, catalytic reactions, and so forth.
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