It was, of course, well known that mere _mixtures_ were entirely
different things from chemical _compounds_. We can mix sand and sugar
together, but they remain sand and sugar, and can be separated again,
having undergone no change. Or we can mix together two liquids or
two gases, and they also can again be separated by suitable means.
But when two substances chemically combine one with another, then we
have some third thing which is entirely different from the original
two, and which possesses properties dissimilar from either. Now, what
has happened when substances thus combine? What are the laws of such
combinations? And what are the ultimate constituents of matter, which
render these combinations possible? Dalton was the first to undertake
an explanation of these phenomena, backed up by experimental evidence.
The historic importance of this cannot be overestimated. As Dr. Raphael
Meldola says, in his “Chemistry”:--
“The doctrine of equivalence, even in its most elastic form, is still
nothing more than a quantitative expression of the facts of chemical
composition. Of course, there must be some underlying principle--some
explanation of this simplicity of multiplicity. Such explanation was
first definitely formulated in 1807-08 by John Dalton, who not only
discovered the law of Multiple Proportions, but suggested a theory, the
introduction of which marks one of the greatest epochs in the history
of Chemistry. The reason why combination takes place in definite
proportions by weight, and why, when the same element has more than
one equivalent the principle of integral multiples is maintained
is, according to Dalton’s explanation, because the combination is
between the ultimate particles of which elementary matter is composed.
This is the notion of the discontinuity or discreteness of matter.
The “particles” of which matter is composed--whatever its state of
aggregation--are, from Dalton’s point of view, ultimate in the sense of
being indivisible. For this reason he called them _atoms_.”
THE ATOMIC THEORY
Here, then, we have at last the Atomic Theory--the theory, that is,
that all matter, in all its stages, is built-up of extremely small
particles which are so small, indeed, that they can no longer be
sub-divided. They are the ultimate of matter--the “building stones of
the Universe”--of which everything, animate and inanimate, is composed.
These atoms were held to be spherical in shape, of a certain definite
weight and figure, according to the element or substance in question.
Thus: “every particle of water is like every other particle of water,
every particle of hydrogen is like every other particle of hydrogen,
etc.” These ultimate particles--atoms--were held to be indestructible.
These atoms all had their own particular _weights_, which might be
denoted by number. Hence “atomic weight.”
These atoms, then, combine, forming molecules, or compounds of atoms;
and molecules make up matter as we see and know it.
Public-domain text, read in full here on John Shaqi.
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