Waters containing organic matter that differs much in quantity from the
examples above may yield very different results and no generalisation
can be made that will cover all cases. An increase of temperature
increases the germicidal velocity and also the rate of absorption of
chlorine by the organic matter; other factors determine which of these
competitive actions predominates.
=Method of Application (admixture).= A thorough admixture of the water
and chlorine is a _sine qua non_ for successful operation. This should,
if possible, be attained by natural means, but if there is any doubt as
to the efficiency of the mixing process, mechanical appliances should be
utilised. Pumps, especially centrifugal pumps, constitute a very
convenient and efficacious method of mixing the germicide and the
water, and the solutions should never be injected into the discharge
pipes when it is possible to make connections with the suctions.
[Illustration: DIAGRAM III
EFFECT OF TEMPERATURE]
[Illustration: DIAGRAM IV
EFFECT OF TEMPERATURE]
Inefficient admixture leads to local concentration of the chlorine, a
condition which (_vide_ p. 35), results in a wastage of the
disinfectant. Two practical examples of this effect may be cited. In one
case the water was free from colour and contained very little organic
matter. This water was chlorinated at one plant by allowing the bleach
solution to drop into one vertical limb of a syphon approximately 6,000
feet long, the other vertical limb being used as a suction well for the
pumps which discharged into the distribution mains. At the other plant
the bleach solution was injected into the discharge pipe of a
reciprocating pump through a pipe perforated with a number of small
holes. The results for two typical months are given in Table X.
TABLE X.--EFFECT OF EFFICIENT MIXING
------+-----------+-----------------------+---------------
| Available | BACTERIA PER C.CM. |
| Chlorine +-----------------------+
| Parts Per | | | B. Coli Index
Month.| Million. | Raw |Treated Water. | Per 100 c.cms.
+-----+-----+ Water.+-------+-------+-------+-------
| A. | B. | | A. | B. | A. | B.
------+-----+-----+-------+-------+-------+-------+-------
July | 0.20| 0.25| 864 | 27 | 93 | <0.2 | 8.5
August| 0.20| 0.27| 1.108 | 12 | 120 | <0.2 | 10.2
------+-----+-----+-------+-------+-------+-------+-------
A = efficient mixing. B = inefficient mixing.
The results with the "B" plant were very irregular. The hypochlorite and
water did not mix thoroughly and, as several suctions pipes were
situated in the suction shaft, there was no subsequent admixture in the
pumps; this also caused complaints regarding taste and odour but the
complaints were localised, and not general as would result from an
overdose of solution due to irregularities at the plant.
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