Chlorine was discovered by the Swedish chemist Scheele in 1774, but he,
like Lavoisier and his pupil Berthollet, who declared it an oxygenated
muriatic acid, was unaware of the elemental nature of the new substance.
Sir Humphrey Davy investigated this body in 1810 and definitely proved
it to be an element; Davy designated the element chlorine from the Greek
[Greek: chlôros] = green.
The first attempt to utilise chlorine, or its compounds, for bleaching
purposes, appears to have been due to James Watt, who noticed the
decolourising properties of chlorine during a visit to Berthollet. This
attempt ended in failure because of the destructive effect on the
fibres, but, in later trials, this was prevented by first absorbing the
gas in a solution of fixed alkali. These experiments proved the
possibility of bleaching by means of chlorine compounds but the high
cost of soda made the process unprofitable, and it was not until Henry
succeeded in preparing a combination with lime that could be reduced to
a dry powder that this mode of chemical bleaching became a commercial
success.
The manufacture of chloride of lime (hypochlorite of lime, bleaching
powder, bleach) was taken up by Charles Tennant in 1799 at St. Rollox
near Glasgow, and in 1800 about 50 tons were sold at a price of $680
(£139) per ton.
Chlorine is produced as a by-product in the manufacture of soda by the
Leblanc process, but until 1865, when the British Alkali Act stopped the
discharge of hydrochloric acid vapours into the atmosphere, the
development of the bleaching powder industry was not rapid. The
hydrochloric acid that was formerly discharged into the air as a waste
product afterwards became a valuable asset that enabled the Leblanc
process to successfully compete with the newer ammonia-soda process. In
1890 another competitor to the Leblanc process was introduced when
caustic and chlorine were produced in Germany by electrolytic methods.
After the successful development of this method in Germany, it was taken
up in the United States of America and in 1912 more than 30,000
electrical horse-power were daily used in this industry. In 1914 the
almost complete cessation of exports of bleach from Europe raised the
price, which attained phenomenal heights in 1916 (cf. page 125), and
stimulated the production of bleach both in the U. S. A. and Canada.
TABLE I.--BLEACH STATISTICS. NORTH AMERICA
Public-domain text, read in full here on John Shaqi.
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