Until a few years ago the non-diaphragm process was the only one used
for water treatment and it will consequently be discussed first.
_Non-diaphragm Process._ The theoretical voltage required for the
decomposition of sodium chloride is 2.3 but when the products recombine
in the electrolyte, side reactions occur which increase the minimum
voltage to 3.54. On this basis one kilowatt hour gives 272 ampere hours
and as one ampere hour is theoretically capable of producing 1.33 grams
of chlorine, 1.21 kilowatt hours are necessary for the production of 1
pound of chlorine by the decomposition of 1.65 pounds of salt.
Charles Watt (1851) discovered this process and was the first to
recognize the necessary conditions which are (1) insoluble electrodes,
(2) low temperature of electrolyte, and (3) rapid circulation of
electrolyte from the cathode to the anode. The control of the
temperature is very important, for as it increases, side reactions occur
with the formation of chlorates, and the efficiency is decreased.
The non-diaphragm cells used in Europe (Haas and Oettel, Kellner,
Hermite, Vogelsand, and Mather and Platt) have been described by
Kershaw.[2] In the Haas and Oettel electrolyser the electrodes are
composed of carbon but in the other types at least one electrode is made
from platinum or a platinum alloy. The Dayton electrolyser, which is the
cell most familiar in North America, is shown in Fig. 9.
[Illustration: FIG. 9.--Dayton Electrolytic Cell.]
The outer cell is made of soapstone and is approximately 2-1/2 feet long
and 2 feet wide. The main electrodes consist of four pieces of Atcheson
graphite connected together by screws and metal strips to which is
attached a clamp for connecting electrical terminals. Circulation of the
brine is produced by glass baffle plates and secondary electrodes placed
one inch apart between the main electrodes. The cell is intended to be
used at 110-volts pressure but by wiring two cells in series a 220-volt
circuit may be employed. An inlet and outlet are provided at each end of
the tank to permit the direction of the flow to be periodically reversed
for the purpose of removing the lime deposit from the graphite plates.
Public-domain text, read in full here on John Shaqi.
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